모든 사진(3)
About This Item
실험식(Hill 표기법):
C17H14B2F8N4Pd
CAS Number:
Molecular Weight:
554.35
MDL number:
UNSPSC 코드:
12161600
NACRES:
NA.22
추천 제품
![1-Chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) >95% in F+ active](/deepweb/assets/sigmaaldrich/product/structures/206/487/53d52ee5-ef71-4e9a-9bc8-938b68b98d5d/640/53d52ee5-ef71-4e9a-9bc8-938b68b98d5d.png)
![(2R,2′R-(+)-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate](/deepweb/assets/sigmaaldrich/product/structures/202/913/41951272-e38c-4f7b-9bf9-6ed9448f4864/640/41951272-e38c-4f7b-9bf9-6ed9448f4864.png)
2 ≥95%](/deepweb/assets/sigmaaldrich/product/structures/276/288/a8ff851d-d6be-43a1-b43f-1438e7b840d7/640/a8ff851d-d6be-43a1-b43f-1438e7b840d7.png)
분석
≥95%
양식
powder or crystals
반응 적합성
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
mp
>300 °C
저장 온도
2-8°C
SMILES string
N#CC.C1(C2=CC=CC=N2)=CC=CC(C3=NC=CC=C3)=N1.[Pd]
InChI
1S/C15H11N3.C2H3N.Pd/c1-3-10-16-12(6-1)14-8-5-9-15(18-14)13-7-2-4-11-17-13;1-2-3;/h1-11H;1H3;
InChI key
UESWWXSSNHGEKT-UHFFFAOYSA-N
애플리케이션
[Pd(terpy)(MeCN)][BF4]2 is a versatile palladium precatalyst.
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관련 제품
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
가장 최신 버전 중 하나를 선택하세요:
Anthony R Mazzotti et al.
Journal of the American Chemical Society, 135(38), 14012-14015 (2013-09-18)
A practical, palladium-catalyzed synthesis of aryl fluorides from arylboronic acid derivatives is presented. The reaction is operationally simple and amenable to multigram-scale synthesis. Evaluation of the reaction mechanism suggests a single-electron-transfer pathway, involving a Pd(III) intermediate that has been isolated
Kumiko Yamamoto et al.
Nature, 554(7693), 511-514 (2018-02-23)
Aryl fluorides are widely used in the pharmaceutical and agrochemical industries, and recent advances have enabled their synthesis through the conversion of various functional groups. However, there is a lack of general methods for direct aromatic carbon-hydrogen (C-H) fluorination. Conventional
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