902144

[(Cp)Ru(η⁶-naphthalene)]OTf

≥95%

• 동의어(들): (η⁵-Cyclopentadienyl)(η⁶-naphthalene)ruthenium(1+) trifluoromethanesulfonate
• 실험식(Hill 표기법): C₁₆H₁₃F₃O₃RuS
• CAS Number: 811794-35-1
• Molecular Weight: 443.40
• UNSPSC 코드: 12352101

속성

• 분석: ≥95%
• 형태: powder
• 반응 적합성: reagent type: catalyst; reaction type: C-C Bond Formation
• mp: 112-116 °C
• 저장 온도: 2-8°C

설명

애플리케이션

Stable precursor for synthesis and ruthenium catalysis. It was also used by the Ritter lab to synthesize an Fmoc-protected ruthenium tyrosine for subsequent incorporation of the [18F]fluoride radiolabel into polypeptides.

기타 정보

Site-Specific Deoxyfluorination of Small Peptides with [18F]Fluoride

Comparison of the Catalytic Activity of [(5-C5H5)Ru(2,2′-bipyridine)(L)]OTf versus [(5-C5H5)Ru(6,6′-diamino-2,2′-bipyridine)(L)]OTf (L = labile ligand) in the Hydrogenation of Cyclohexanone. Evidence for the Presence of a Metal–Ligand Bifunctional Mechanism under Acidic Conditions

Arene Exchange in the Ruthenium-Naphthalene Complex [CpRu(C10H8)]+

안전성 정보

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable