추천 제품
![Chloro(4-cyanophenyl)[(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldiphenylphosphine]nickel(II) ≥95%](/deepweb/assets/sigmaaldrich/product/structures/340/487/46acce30-30a6-440b-9b5e-6850d2becdc3/640/46acce30-30a6-440b-9b5e-6850d2becdc3.png)
![Chloro(4-cyanophenyl)[(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine]nickel(II)](/deepweb/assets/sigmaaldrich/product/structures/308/161/648149e1-191f-48a0-af54-81c827b98fc9/640/648149e1-191f-48a0-af54-81c827b98fc9.png)
![Chloro(4-cyanophenyl)[(R)-1-[(S)-2-[bis(4-fluorophenyl]phosphino]ferrocenyl]ethyldi-tert-butylphosphine]nickel(II) ≥95%](/deepweb/assets/sigmaaldrich/product/structures/254/853/77d2cb57-4a1a-431b-a86a-6ccb7e76206b/640/77d2cb57-4a1a-431b-a86a-6ccb7e76206b.png)
![Chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]copper(I)](/deepweb/assets/sigmaaldrich/product/structures/199/763/44637b2e-b87c-42a3-abc3-3985b6cd7d5d/640/44637b2e-b87c-42a3-abc3-3985b6cd7d5d.png)
![[(TMEDA)Ni(o-tolyl)Cl] 95%](/deepweb/assets/sigmaaldrich/product/structures/236/439/768c916e-994f-47e3-a980-3ca0471317d7/640/768c916e-994f-47e3-a980-3ca0471317d7.png)
Quality Level
분석
≥95%
형태
powder or solid
반응 적합성
core: nickel
reaction type: Cross Couplings
reagent type: catalyst
reaction type: Asymmetric synthesis
SMILES string
CC(C)(C)P(C(C)(C)C)C[C]1[C][C][C][C]1P(C2=CC=CC=C2)C3=CC=CC=C3.[Ni+2]C4=CC=C(C#N)C=C4.[C]5[C][C][C][C]5.[Fe]
애플리케이션
Amination of aryl chlorides with ammonia.
관련 제품
제품 번호
설명
가격
신호어
Warning
유해 및 위험 성명서
Hazard Classifications
Aquatic Chronic 2 - Repr. 2 - Skin Irrit. 2
Storage Class Code
4.1B - Flammable solid hazardous materials
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
시험 성적서(COA)
제품의 로트/배치 번호를 입력하여 시험 성적서(COA)을 검색하십시오. 로트 및 배치 번호는 제품 라벨에 있는 ‘로트’ 또는 ‘배치’라는 용어 뒤에서 찾을 수 있습니다.
Ni?Catalyzed Amination Reactions: An Overview.
Marin M, et al.
Chemical Record, 16(4), 1819-1832 (2016)
Nickel?Catalyzed Amination of Aryl Chlorides with Ammonia or Ammonium Salts.
Green R A and Hartwig J F
Angewandte Chemie (International Edition in English), 54(12), 3768-3772 (2015)
Evaluating 1, 1?-Bis (phosphino) ferrocene Ancillary Ligand Variants in the Nickel-Catalyzed C?N Cross-Coupling of (Hetero) aryl Chlorides.
Clark J S, et al.
Organometallics, 36(3), 679-686 (2017)
Nickel?Catalyzed Monoarylation of Ammonia.
Borzenko A, et al.
Angewandte Chemie (International Edition in English), 54(12), 3773-3777 (2015)
Sarah Z Tasker et al.
Nature, 509(7500), 299-309 (2014-05-16)
Tremendous advances have been made in nickel catalysis over the past decade. Several key properties of nickel, such as facile oxidative addition and ready access to multiple oxidation states, have allowed the development of a broad range of innovative reactions.
자사의 과학자팀은 생명 과학, 재료 과학, 화학 합성, 크로마토그래피, 분석 및 기타 많은 영역을 포함한 모든 과학 분야에 경험이 있습니다..
고객지원팀으로 연락바랍니다.