89025

Copper(I) thiophenolate

≥98.0% (RT)

• 동의어(들): PhSCu, Copper(I) thiophenoxide, Phenylthiocopper(I), Thiophenol copper(I) salt
• Linear Formula: C₆H₅SCu
• CAS Number: 1192-40-1
• Molecular Weight: 172.71
• Beilstein: 3709171
• MDL number: MFCD00064893
• UNSPSC 코드: 12352300
• PubChem Substance ID: 24889167
• NACRES: NA.22

속성

• 분석: ≥98.0% (RT)
• 양식: solid
• 반응 적합성: core: copper; reagent type: catalyst
• mp: 280 °C (dec.) (lit.)
• SMILES string: [Cu]Sc1ccccc1
• InChI: 1S/C6H6S.Cu/c7-6-4-2-1-3-5-6;/h1-5,7H;/q;+1/p-1
• InChI key: PNNJYDODNCALKD-UHFFFAOYSA-M

설명

애플리케이션

Reagents used as the source of nucleophilic phenyl sulfide for preparation of lithiumalkyl(phenylthio)cuprates and organophosphinecopper(I) phenylthiolatecomplexes

기타 정보

Reagent for the simple preparation of lithium (phenylthio)alkyl-cuprates from lithium alkyls, used for conjugate addition to α,β-enones

안전성 정보

• 픽토그램: GHS05
• 신호어: Danger
• 유해 및 위험 성명서: H314
• 예방조치 성명서: P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
• Hazard Classifications: Skin Corr. 1B
• Storage Class Code: 8A - Combustible corrosive hazardous materials
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges