추천 제품
양식
liquid
반응 적합성
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
전이 온도
flash point 42.0 °F
작용기
phosphine
저장 온도
2-8°C
SMILES string
COC(C=CC=C1OC)=[C@]1[C@@]2=C([P@](C(C)(C)C)[C@@H](CC3=C(C(C)C)C=C(C(C)C)C=C3C(C)C)O4)C4=CC=C2
애플리케이션
HandaPhos is a monophosphine ligand. As reported by Lipshutz and coworkers, HandaPhos, in tandem with designer surfactant TPGS-750-M, allows for palladium-catalyzed cross-couplings to be performed at room temperature requiring levels of palladium lower than 1000 ppm (less than 0.1 mol %). HandaPhos can be used in cross-couplings such as Suzuki-Miyaura, Sonogashira, Buchwald-Hartwig and several other commonly used cross-coupling reactions.
기타 정보
Watch Professor Lipshutz talk about HandaPhos in this webinar:
From milligrams to kilograms: synthetic chemistry following nature′s lead
From milligrams to kilograms: synthetic chemistry following nature′s lead
관련 제품
제품 번호
설명
가격
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Aquatic Chronic 3 - Asp. Tox. 1 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 2 - STOT SE 3
표적 기관
Central nervous system
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point (°F)
41.0 °F
Flash Point (°C)
5 °C
가장 최신 버전 중 하나를 선택하세요:
Micellar catalysis-enabled sustainable ppm Au-catalyzed reactions in water at room temperature.
Klumphu P, et al.
Chemical Science, 8(9), 6354-6358 (2017)
Synthetic Chemistry in a Water World. New Rules Ripe for Discovery.
Lipshutz B H
Current opinion in green and sustainable chemistry., 11, 1-8 (2018)
Sustainable HandaPhos-ppm Palladium Technology for Copper-Free Sonogashira Couplings in Water under Mild Conditions.
Handa S, et al.
Organic Letters, 20 (3), 542?545-542?545 (2018)
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