798835

[Ru(phd)₃](PF₆)₂

• 동의어(들): Tris(1,10-phenanthroline-5,6-dione)ruthenium(II) bis(hexafluorophosphate)
• 실험식(Hill 표기법): C₃₆H₁₈F₁₂N₆O₆P₂Ru
• CAS Number: 184023-77-6
• Molecular Weight: 1021.56
• UNSPSC 코드: 12352202
• PubChem Substance ID: 329768673
• NACRES: NA.22

속성

• 양식: powder
• 반응 적합성: core: ruthenium; reagent type: catalyst
• SMILES string: F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.O=C1C2=C(C3=NC=CC=C3C1=O)N=CC=C2.O=C4C(C=CC=N5)=C5C6=C(C4=O)C=CC=N6.O=C7C8=CC=CN=C8C9=C(C7=O)C=CC=N9.[Ru+2]
• InChI: 1S/3C12H6N2O2.2F6P.Ru/c3*15-11-7-3-1-5-13-9(7)10-8(12(11)16)4-2-6-14-10;2*1-7(2,3,4,5)6;/h3*1-6H;;;/q;;;2*-1;+2
• InChI key: LGAOGZFZNIEFHF-UHFFFAOYSA-N

설명

애플리케이션

In combination with Co(salophen), (Aldrich 345652), [Ru(phd)₃](PF₆)₂ is utilized in the aerobic oxidation of tetrahydroquinolines at room temperature to form quinolines. Unlike previous catalyst systems, the reported application is highly efficient under the presence of atmospheric oxygen.

법적 정보

Modular o-Quinone Catalyst System for Dehydrogenation of Tetrahydroquinolines under Ambient Conditions

안전성 정보

• Storage Class Code: 13 - Non Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable