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Merck
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주요 문서

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723274

Sigma-Aldrich

4-Cyano-4-[(dodecylsulfanylthiocarbonyl)sulfanyl]pentanoic acid

97% (HPLC)

동의어(들):

4-Cyano-4-(((dodecylthio)carbonothioyl)thio)pentanoic acid

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모든 사진(3)

About This Item

실험식(Hill 표기법):
C19H33NO2S3
CAS Number:
870196-80-8
Molecular Weight:
403.67
MDL number:
MFCD11040288
UNSPSC 코드:
12352100
PubChem Substance ID:
329763992
NACRES:
NA.23

Quality Level

100

분석

97% (HPLC)

양식

solid

mp

64-68 °C

저장 온도

−20°C

SMILES string

CCCCCCCCCCCCSC(=S)SC(C)(CCC(O)=O)C#N

InChI

1S/C19H33NO2S3/c1-3-4-5-6-7-8-9-10-11-12-15-24-18(23)25-19(2,16-20)14-13-17(21)22/h3-15H2,1-2H3,(H,21,22)

InChI key

RNTXYZIABJIFKQ-UHFFFAOYSA-N

관련 카테고리

일반 설명

Need help choosing the correct RAFT Agent? Please consult the RAFT Agent to Monomer compatibility table.

애플리케이션

Reversible Addition Fragmentation Chain Transfer (RAFT) Polymerization

픽토그램

Exclamation mark
GHS07

신호어

Warning

유해 및 위험 성명서

H302

Hazard Classifications

Acute Tox. 4 Oral

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

가장 최신 버전 중 하나를 선택하세요:

시험 성적서(COA)

Lot/Batch Number
MKCP1511
MKCL9888
MKCL2319
MKCL2318
MKCJ9315

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특정 버전이 필요한 경우 로트 번호나 배치 번호로 특정 인증서를 찾을 수 있습니다.

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Katharina Hendrich et al.
Polymers, 12(6) (2020-05-30)
Linear and four-arm star polystyrene samples prepared by RAFT polymerization were grafted to gold surfaces directly via their thiocarbonylthio-end groups. Nanoscale polymer patterns were subsequently formed via constrained dewetting. The patterned polymer films then served as a template for the
RAFT Agent Design and Synthesis
Keddie, D. J.; et al.
Macromolecules, 45, 5321-5342 (2012)
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문서

Select RAFT Agents for Making Well-Defined Functionalized Polymers

The supply of low cost, high purity and effective Reversible addition−fragmentation chain-transfer (RAFT) Agents is the essential element in the industrial implementation of RAFT polymerization technology.

Evaluation of RAFT Agents

A series of polymerization were carried out using RAFT agents and monomers yielding well-defined polymers with narrow molecular weight distributions. The process allows radical-initiated growing polymer chains to degeneratively transfer reactivity from one to another through the use of key functional groups (dithioesters, trithiocarbonates, xanthates and dithiocarbamates). RAFT agents help to minimize out-of-control growth and prevent unwanted termination events from occurring, effectively controlling polymer properties like molecular weight and polydispersity. RAFT agents are commercially available. RAFT does not use any cytotoxic heavy metal components (unlike ATRP).

Reversible Addition Fragmentation Chain Transfer (RAFT) Polymerization

RAFT (Reversible Addition Fragmentation chain Transfer) polymerization is a reversible deactivation radical polymerization (RDRP) and one of the more versatile methods for providing living characteristics to radical polymerization.

Functional Biomaterials Synthesized by Double-Head Polymerization Agents

Over the past two decades, the rapid advance of controlled living polymerization (CLP) techniques.

모두 보기

프로토콜

Concepts and Tools for RAFT Polymerization

Sigma-Aldrich presents an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Typical Procedures for Polymerizing via RAFT

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

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