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700762

(S)-SIPHOS-PE

Name: (<I>S</I>)-SIPHOS-PE
Brand: ALDRICH

97%

동의어(들):

(11aS)-(−)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1′, 7′-fg][1,3,2]dioxaphosphocin-5-bis[(R)-1-phenylethyl]amine, N-Di[(R)-1-phenylethyl]-[(S)-1,1′-spirobiindane-7,7′-diyl]-phosphoramidite

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About This Item

실험식(Hill 표기법):

C₃₃H₃₂NO₂P

CAS Number:

500997-70-6

Molecular Weight:

505.59

MDL number:

MFCD08459342

UNSPSC 코드:

12352005

PubChem Substance ID:

329762229

NACRES:

NA.22

추천 제품

Slide 1 of 10

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Sigma-Aldrich

665290

(S,S,S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a′]dinaphthalen-4-yl)bis(1-phenylethyl)amine

Sigma-Aldrich

665347

(S,R)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a′]dinaphthalen-4-yl)-(1-phenylethyl)amine

Sigma-Aldrich

668192

(S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a;3,4- a′]dinaphthalen-4-yl)dimethylamine

Sigma-Aldrich

665363

(S,R,R)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a′]dinaphthalen-4-yl)bis(1-phenylethyl)amine

Sigma-Aldrich

912719

(S)-BIDIME

Sigma-Aldrich

904961

Feng L₃-PrPr₂

Sigma-Aldrich

T511609

(S)-TCYP

Sigma-Aldrich

232238

Pyridinium p-toluenesulfonate

Sigma-Aldrich

680184

(S)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate

Sigma-Aldrich

905240

(R,R,R)-SPIRAP

Quality Level

100

분석

97%

형태

powder

광학 활성

[α]22/D −65.0°, c = 1 in chloroform

mp

120-125 °C

작용기

amine
phenyl

저장 온도

−20°C

SMILES string

C[C@@H](N([C@H](C)c1ccccc1)P2Oc3cccc4CCC5(CCc6cccc(O2)c56)c34)c7ccccc7

InChI

1S/C33H32NO2P/c1-23(25-11-5-3-6-12-25)34(24(2)26-13-7-4-8-14-26)37-35-29-17-9-15-27-19-21-33(31(27)29)22-20-28-16-10-18-30(36-37)32(28)33/h3-18,23-24H,19-22H2,1-2H3/t23-,24-,33?/m1/s1

InChI key

ZXLQLIDJAURBDD-HRPAVAKOSA-N

애플리케이션

(S)-SIPHOS-PE is a chiral spiro phosphoramidate ligand that can be used to synthesize:

Spiroindolenines by Pd-catalyzed intramolecular dearomative arylation of haloaryl-3-substituted indoles.
Enantioselective conjugate addition compound by Cu-catalyzed 1,4-addition of diethylzinc (Et₂Zn) to cyclic enones.
Octaketide natural products via rhodium-phosphoramidite catalyzed alkene hydroacylation.