693057

(S)-BINAP

• 동의어(들): (S)-(−)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene, (S)-(−)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl, (S)-(−)-(1,1′-Binaphthalene-2,2′-diyl)bis(diphenylphosphine), (S)-(−)-BINAP
• Linear Formula: [(C₆H₅)₂PC₁₀H₆-]₂
• CAS Number: 76189-56-5
• Molecular Weight: 622.67
• Beilstein: 5321443
• MDL number: MFCD00010805
• UNSPSC 코드: 12352005
• PubChem Substance ID: 329761558
• NACRES: NA.22

속성

• 양식: crystals
• Quality Level: 100
• 광학 활성: [α]20/D -222, c = 0.5 in benzene
• mp: 238-240 °C (lit.)
• 작용기: phosphine
• SMILES string: P(c8ccccc8)(c7ccccc7)c1c(c6c(cc1)cccc6)c2c3c(ccc2P(c5ccccc5)c4ccccc4)cccc3
• InChI: 1S/C44H32P2/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38/h1-32H
• InChI key: MUALRAIOVNYAIW-UHFFFAOYSA-N

설명

애플리케이션

Takasago Ligands and Complexes for Asymmetric Reactions

Reactant involved in:

• Enantioselective and diastereoselective unpoled carbonyl allylation
• Syntehsis of organophophine oxides as anittumor agents
• SN2 halogenation of hydroxy groups
• Synthesis of BINAP complexes
• Studies of conformational flexibility of BINAP chelates

법적 정보

Sold in collaboration with Takasago for research purposes only.

안전성 정보

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: Eyeshields, Gloves, type N95 (US)