676004

(R)-(+)-2,2′,6,6′-Tetramethoxy-4,4′-bis(di(3,5-xylyl)phosphino)-3,3′-bipyridine

97%

• 동의어(들): (R)-Xylyl-P-Phos
• 실험식(Hill 표기법): C₄₆H₅₀N₂O₄P₂
• CAS Number: 442905-33-1
• Molecular Weight: 756.85
• MDL number: MFCD04974235
• UNSPSC 코드: 12352005
• PubChem Substance ID: 24885316
• NACRES: NA.22

속성

• Quality Level: 100
• 분석: 97%
• 양식: solid
• 광학 활성: [α]20/D +125°, c = 1 in chloroform
• mp: 190-194 °C
• 작용기: phosphine
• SMILES string: COc1cc(P(c2cc(C)cc(C)c2)c3cc(C)cc(C)c3)c(c(OC)n1)-c4c(OC)nc(OC)cc4P(c5cc(C)cc(C)c5)c6cc(C)cc(C)c6
• InChI: 1S/C46H50N2O4P2/c1-27-13-28(2)18-35(17-27)53(36-19-29(3)14-30(4)20-36)39-25-41(49-9)47-45(51-11)43(39)44-40(26-42(50-10)48-46(44)52-12)54(37-21-31(5)15-32(6)22-37)38-23-33(7)16-34(8)24-38/h13-26H,1-12H3
• InChI key: JRTHAKOHBMETRC-UHFFFAOYSA-N

설명

애플리케이션

Ligand employed in the asymmetic hydrogenation of ß-keto esters, 2-arylacrylates, aryl ketones , and other substrates.

법적 정보

Sold in collaboration with Johnson Matthey Catalyst for research purposes only. US5886182 and any patents arising therefrom apply.

안전성 정보

• 픽토그램: GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H315,H319,H335
• 예방조치 성명서: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 표적 기관: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: dust mask type N95 (US), Eyeshields, Gloves