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593192

Cu-TMEDA catalyst

Name: Cu-TMEDA catalyst
Brand: ALDRICH

동의어(들):

Di-μ-hydroxo-bis[(N,N,N′.N′-tetramethylethylenediamine)copper(II)] chloride

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About This Item

실험식(Hill 표기법):

C₁₂H₃₄Cl₂Cu₂N₄O₂

CAS Number:

30698-64-7

Molecular Weight:

464.42

MDL number:

MFCD01321163

UNSPSC 코드:

12161600

PubChem Substance ID:

24881335

NACRES:

NA.22

추천 제품

Slide 1 of 10

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Sigma-Aldrich

411019

N,N,N′,N′-Tetramethylethylenediamine

Sigma-Aldrich

139009

1,8-Diazabicyclo[5.4.0]undec-7-ene

Sigma-Aldrich

D125806

N,N-Diisopropylethylamine

Sigma-Aldrich

562254

4-Chloro-3-fluorophenylmagnesium bromide solution

Sigma-Aldrich

283673

Copper(II) trifluoromethanesulfonate

Sigma-Aldrich

677892

Tetrakis(acetonitrile)copper(I) tetrafluoroborate

Sigma-Aldrich

697257

Copper(I) cyanide di(lithium chloride) complex solution

Sigma-Aldrich

T22500

N,N,N′,N′-Tetramethylethylenediamine

Sigma-Aldrich

8.08742

N,N,N′,N′-Tetramethyl ethylenediamine

Sigma-Aldrich

346276

Tetrakis(acetonitrile)copper(I) hexafluorophosphate

반응 적합성

core: copper
reagent type: catalyst

mp

131-132 °C (lit.)

SMILES string

[H]O[Cu]Cl.[H]O[Cu]Cl.CN(C)CCN(C)C.CN(C)CCN(C)C

InChI

1S/2C6H16N2.2ClH.2Cu.2H2O/c2*1-7(2)5-6-8(3)4;;;;;;/h2*5-6H2,1-4H3;2*1H;;;2*1H2/q;;;;2*+2;;/p-4

InChI key

XSGFQMSXIWLPOB-UHFFFAOYSA-J

애플리케이션

Catalyst for:

Asymmetric conjugate addition reactions
1,3-dipolar cycloaddition of pyrazolidinone-based dipoles to terminal alkynes (precatalyst)
Oxidative N-arylation of imidazoles
Oxidative coupling copolymerization
Tandem phosphorous-carbon bond formation-oxyfunctionalization reactions
Benzylation and allylation of amides