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Merck
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주요 문서

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592684

Sigma-Aldrich

Bis(dimethylphosphino)methane

97%

동의어(들):

DMPM

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About This Item

Linear Formula:
(CH3)2PCH2P(CH3)2
CAS Number:
64065-08-3
Molecular Weight:
136.11
MDL number:
MFCD00058731
UNSPSC 코드:
12352001
PubChem Substance ID:
24881405
NACRES:
NA.22

분석

97%

반응 적합성

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

refractive index

n20/D 1.5060 (lit.)

bp

42 °C/12 mmHg (lit.)

density

0.86 g/mL at 25 °C (lit.)

작용기

phosphine

SMILES string

CP(C)CP(C)C

InChI

1S/C5H14P2/c1-6(2)5-7(3)4/h5H2,1-4H3

InChI key

MRNJHNUEBDGNEL-UHFFFAOYSA-N

애플리케이션

Reactant for:
  • Preparation of ruthenium carbonyl hydrido phosphanido diphosphine dinuclear complexes
  • Luminescent face-to-face dinuclear platinum(II) alkynyl phosphine complexes
  • Phosphorus-phosphorus bond and nuclear spin-spin coupling
  • Formation of a catalytic ruthenium(II)-triphos complex

Catalyst for:
  • Asymmetric alkylation of racemic secondary phosphines
  • Palladium-diphosphine catalyzed carbonylation of ethene

픽토그램

Flame
GHS02

신호어

Danger

유해 및 위험 성명서

H250

예방조치 성명서

P222 - P231 - P422

Hazard Classifications

Pyr. Liq. 1

Storage Class Code

4.2 - Pyrophoric and self-heating hazardous materials

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

가장 최신 버전 중 하나를 선택하세요:

시험 성적서(COA)

Lot/Batch Number
SHBG2515V
56496HKV
56496HK
23019BB
08424AB

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문서 라이브러리 방문

Graziella Cimino-Reale et al.
Journal of hematology & oncology, 10(1), 140-140 (2017-07-19)
Understanding the molecular/cellular underpinnings of diffuse malignant peritoneal mesothelioma (DMPM), a fatal malignancy with limited therapeutic options, is of utmost importance for the fruitful management of the disease. In this context, we previously found that telomerase activity (TA), which accounts
Jana Elias et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 25(26), 6553-6561 (2019-03-02)
A new boron-boron dehydrocoupling strategy was established, providing convenient access to some diborane(4) compounds starting from simple borane adducts under mild conditions. In contrast to the traditional pathway using a reducing reagent, the reduction from BIII to BII was paradoxically
Giovanna Li Petri et al.
British journal of cancer, 123(4), 644-656 (2020-06-05)
Expression of proton-coupled folate transporter (PCFT) is associated with survival of mesothelioma patients treated with pemetrexed, and is reduced by hypoxia, prompting studies to elucidate their correlation. Modulation of glycolytic gene expression was evaluated by PCR arrays in tumour cells
Michelandrea De Cesare et al.
Oncotarget, 6(15), 13119-13132 (2015-05-08)
Survivin, which is highly expressed and promotes cell survival in diffuse malignant peritoneal mesothelioma (DMPM), exclusively relies on exportin 1 (XPO1/CRM1) to be shuttled into the cytoplasm and perform its anti-apoptotic function. Here, we explored the efficacy of Selective Inhibitors

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