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540080

Sigma-Aldrich

(S)-(+)-Epichlorohydrin

98%

동의어(들):

(S)-(+)-2-(Chloromethyl)oxirane

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About This Item

실험식(Hill 표기법):
C3H5ClO
CAS Number:
67843-74-7
Molecular Weight:
92.52
Beilstein:
1420784
MDL number:
MFCD00077760
UNSPSC 코드:
12352005
PubChem Substance ID:
24878439
NACRES:
NA.22

vapor density

3.2 (vs air)

Quality Level

200

vapor pressure

12.5 mmHg ( 20 °C)

분석

98%

광학 활성

[α]20/D +35°, c = 1 in methanol

광학 순도

ee: 97% (GLC)

autoignition temp.

1421 °F

expl. lim.

21 %

refractive index

n20/D 1.438 (lit.)

bp

92-93 °C/360 mmHg (lit.)

density

1.183 g/mL at 25 °C (lit.)

SMILES string

ClC[C@@H]1CO1

InChI

1S/C3H5ClO/c4-1-3-2-5-3/h3H,1-2H2/t3-/m1/s1

InChI key

BRLQWZUYTZBJKN-GSVOUGTGSA-N

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애플리케이션

Chiral building block in the enantioselective syntheses of hydroxyisoxazolidines and (+)-cis-sylvaticin, a potential antitumor agent.
Used in the total synthesis of Macquarimicins and in the total synthesis of the macrolide RK-397.
Used to synthesize inhibitors of fatty acid oxidation as potential metabolic modulators.

법적 정보

Manufactured under license by Sterling Pharma Solutions Limited, using Jacobsen HKR technology.

신호어

Danger

유해 및 위험 성명서

H226,H301 + H311 + H331,H314,H317,H350

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Carc. 1B - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - Skin Sens. 1

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point (°F)

89.6 °F - closed cup

Flash Point (°C)

32 °C - closed cup

개인 보호 장비

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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시험 성적서(COA)

Lot/Batch Number
13105DE
14430PI
12416CC
07204AA

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문서 라이브러리 방문

Timothy J Donohoe et al.
Journal of the American Chemical Society, 128(42), 13704-13705 (2006-10-19)
The double oxidative cyclization of dienes is a viable procedure for making complex natural products containing cis-THF units. A double deprotection/double oxidative cyclization strategy using catalytic osmium tetroxide was used to construct the bisheterocyclic core of cis-sylvaticin and ultimately confirm
Ryosuke Munakata et al.
Journal of the American Chemical Society, 125(48), 14722-14723 (2003-12-04)
The first total synthesis of (+)-macquarimicin A (1), a novel inhibitor of neutral sphingomyelinase (N-SMase) with antiinflammatory activity, has been accomplished. The present work determined the absolute configuration of (+)-1 and revised the C(2)-C(3) geometry to be Z. The synthesis
Elfatih Elzein et al.
Bioorganic & medicinal chemistry letters, 14(4), 973-977 (2004-03-12)
We describe the synthesis of novel inhibitors of fatty acid oxidation as potential metabolic modulators for the treatment of stable angina. Replacement of the 2H-benzo[d]1,3-dioxolene ring system in our initial lead 3 with different benzthiazoles, benzoxazoles and introducing small alkyl
Tetrahedron Letters, 47, 7635-7635 (2006)
Svetlana A Burova et al.
Journal of the American Chemical Society, 126(8), 2495-2500 (2004-02-26)
The total synthesis of the natural product RK-397 is based on a new synthetic strategy for assembling polyacetate structures, by efficient cross-coupling of nucleophilic terminal alkyne modules with electrophilic epoxides bearing another alkyne at the opposite terminus. The natural product
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