498041

Cyclopentylzinc bromide solution

0.5 M in THF

• 동의어(들): Bromo(cyclopentyl)zinc, Bromocyclopentylzinc
• Linear Formula: C₅H₉ZnBr
• CAS Number: 171860-68-7
• Molecular Weight: 214.42
• MDL number: MFCD00671991
• UNSPSC 코드: 12352103
• PubChem Substance ID: 24873166
• NACRES: NA.22

속성

• 농도: 0.5 M in THF
• density: 0.955 g/mL at 25 °C
• 저장 온도: 2-8°C
• SMILES string: Br[Zn]C1CCCC1
• InChI: 1S/C5H9.BrH.Zn/c1-2-4-5-3-1;;/h1H,2-5H2;1H;/q;;+1/p-1
• InChI key: GOPYCBPMCCJYSN-UHFFFAOYSA-M

설명

애플리케이션

Cyclopentylzinc bromide is an organozinc reagent that can be used in:

• The synthesis of polyfunctional indoles by reacting with various aryldiazonium salts via Fischer indole synthesis.
• Negishi cross-coupling reactions with various haloarenes in presence of Pd-complex catalyst.
• The preparation of aryl alkyl ketones by alkylation of aryl N-methyl-N-tosyl or N-benzyl-N-(tert-butoxycarbonyl) amide derivatives in the presence of Ni catalyst and imidazolidinylidene ligand.

법적 정보

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

안전성 정보

• 픽토그램: GHS02,GHS08,GHS07
• 신호어: Danger
• 유해 및 위험 성명서: H225,H261,H302,H315,H319,H335,H351
• 예방조치 성명서: P210 - P231 + P232 - P280 - P370 + P378 - P402 + P404 - P403 + P235
• Hazard Classifications: Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3 - Water-react 2
• 표적 기관: Respiratory system
• 보충제 위험성: EUH019
• Storage Class Code: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 3
• Flash Point (°F): 1.4 °F - closed cup
• Flash Point (°C): -17 °C - closed cup