449563

Borane diphenylphosphine complex

98%

• 동의어(들): (Diphenylphosphine)trihydroboron
• Linear Formula: (C₆H₅)₂PH·BH₃
• CAS Number: 41593-58-2
• Molecular Weight: 200.02
• MDL number: MFCD00274254
• UNSPSC 코드: 12352002
• PubChem Substance ID: 24868492
• NACRES: NA.22

속성

• Quality Level: 100
• 분석: 98%
• 형태: solid
• 반응 적합성: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand; reaction type: Reductions; reagent type: reductant
• bp: 148-150 °C/10 mmHg (lit.)
• mp: 47-50 °C (lit.)
• 작용기: phosphine
• SMILES string: B.[H]P(c1ccccc1)c2ccccc2
• InChI: 1S/C12H11P.BH3/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10,13H;1H3
• InChI key: XUFGOLYVDOBYLK-UHFFFAOYSA-N

설명

애플리케이션

Reactant for:

• Nucleophilic addition reactions (anion)
• Catalytic dehydrogenation in the presence of ruthenium bidentate phosphine compelxes
• Deprotonation reactions
• Catalytic coupling with alkynyl bromides
• Catalyst-free Staudinger ligation for indirect 18F-radiolabeling
• Preparation of chiral phosphine-phosphite bidentate ligands with biphenyl backbone
• Reactions with frustrated lewis pair combinations of group 14 triflates and sterically hindered nitrogen bases

안전성 정보

• 픽토그램: GHS02
• 신호어: Danger
• 유해 및 위험 성명서: H261
• 예방조치 성명서: P231 + P232 - P422
• Hazard Classifications: Water-react 2
• Storage Class Code: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: Eyeshields, Gloves, type P3 (EN 143) respirator cartridges