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Key Documents

431567

Sigma-Aldrich

Lithium perchlorate

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99.99% trace metals basis

동의어(들):

Perchloric acid, lithium salt

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About This Item

Linear Formula:
LiClO4
CAS Number:
Molecular Weight:
106.39
EC Number:
MDL number:
UNSPSC 코드:
12352302
PubChem Substance ID:
NACRES:
NA.23

Grade

ACS reagent

분석

99.99% trace metals basis

형태

granular

반응 적합성

reagent type: oxidant

환경친화적 대안 제품 특성

Design for Energy Efficiency
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sustainability

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불순물

≤0.005% insolubles
<100 ppm total metallic impurities

pH

6.0-7.5

mp

236 °C (lit.)

solubility

H2O: 106.4 g/L at 20 °C

음이온 미량물

chloride (Cl-): ≤0.003%
sulfate (SO42-): ≤0.001%

환경친화적 대안 카테고리

SMILES string

[Li+].[O-]Cl(=O)(=O)=O

InChI

1S/ClHO4.Li/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1

InChI key

MHCFAGZWMAWTNR-UHFFFAOYSA-M

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일반 설명

Lithium perchlorate is a white salt that easily dissolves in water. It is commonly employed as an electrolytic salt in batteries due to its excellent electrical impedance, conductivity, hygroscopicity, and anodic stability properties. These characteristics are crucial for its role in battery applications. In addition, it is as a strong oxidizing agent and hence is used as an oxidizer in solid rocket propellants and organic reactions.
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애플리케이션

Lithium perchlorate can be used:
  • As a precursor to prepare solid polymer electrolytes for rechargeable Li-ion batteries.
  • As an oxidizer to prepare polymer-based solid propellants.
  • To fabricate cobalt sulfide (CoS)-based counter electrode for dye-sensitized solar cells(DSSC).
Our Lithium perchlorate, with a 99.99% trace metals basis, possesses specific specifications that make it ideal for Lithium-ion batteries. It has low levels of anion traces such as chloride (Cl-): ≤0.003%and sulfate (SO42-): ≤0.001%. Additionally, it contains less than 5 ppm of heavy metals, further enhancing its suitability as an electrolytic salt for Lithium-ion batteries.

픽토그램

Flame over circleCorrosionExclamation mark

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Ox. Sol. 2 - Skin Corr. 1A - STOT SE 3

표적 기관

Respiratory system

Storage Class Code

5.1A - Strongly oxidizing hazardous materials

WGK

WGK 1

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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문서 라이브러리 방문

Shokaku Kim et al.
Organic letters, 4(21), 3735-3737 (2002-10-12)
[reaction: see text] N-Acyliminium cation of prolines was efficiently generated to accumulate in an undivided cell at 0 degrees C by an anodic oxidation of N-acylprolines or alpha'-phenylsulfanylated N-acylproline derivatives in a lithium perchlorate/nitromethane solution. The iminium cation intermediates gave
L H Sim et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 76(3-4), 287-292 (2010-05-07)
The interaction behaviours between components of polyacrylate (PAc)/poly(ethylene oxide) (PEO) and lithium perchlorate (LiClO(4)) were investigated in detail by Attenuated Total Reflectance (ATR)-Fourier Transformed Infrared (FTIR) spectroscopy. Solution cast films of the PAc/PEO and PAc/PEO/LiClO(4) were examined. No obvious shifting
Natalia Varaksa et al.
Proceedings of the National Academy of Sciences of the United States of America, 99(8), 5012-5017 (2002-04-18)
The adsorption of the trigonal connector, 1,3,5-tris[10-(3-ethylthiopropyl)dimethylsilyl-1,10-dicarba-closo-decaboran-1-yl]benzene (1), from acetonitrile/0.1 M LiClO(4) on the surface of mercury at potentials ranging from +0.3 to -1.4 V (vs. aqueous Ag/AgCl/1 M LiCl) was examined by voltammetry, Langmuir isotherms at controlled potentials, and
Witold Darlewski et al.
Journal of hazardous materials, 175(1-3), 460-467 (2009-11-17)
A process of dibutyl sulphide (DBS) electro-oxidation using electrolysis and cyclic voltamperometry was investigated in water-methanol solution using different electrodes (platinum, boron doped diamond, graphite and glassy carbon). Obtained results indicate that the DBS electro-oxidation process is irreversible in voltamperometric
Francisco Palacios et al.
The Journal of organic chemistry, 67(7), 2131-2135 (2002-04-02)
Functionalized keto-enamines 6 were obtained by nucleophilic addition of enol ethers to the imine moiety of 2-azadienes derived from dehydroaspartic esters 4. Reactions of 2-azadiene 4c containing three electron-withdrawing substituents (CO(2)R) with enol ethers 5 in the presence of lithium

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