429937

Triisopropylsilanethiol

97%

• 동의어(들): 1,1,1-Tris(1-methylethyl)silanethiol, Triisopropylsilylthiol, Tris(propan-2-yl)silanethiol
• Linear Formula: [(CH₃)₂CH]₃SiSH
• CAS Number: 156275-96-6
• Molecular Weight: 190.42
• MDL number: MFCD00216593
• UNSPSC 코드: 12352103
• PubChem Substance ID: 24866902
• NACRES: NA.22

속성

• Quality Level: 100
• 분석: 97%
• 양식: liquid
• refractive index: n20/D 1.479 (lit.)
• bp: 70-75 °C/2 mmHg (lit.)
• density: 0.887 g/mL at 25 °C (lit.)
• SMILES string: CC(C)[Si](S)(C(C)C)C(C)C
• InChI: 1S/C9H22SSi/c1-7(2)11(10,8(3)4)9(5)6/h7-10H,1-6H3
• InChI key: CPKHFNMJTBLKLK-UHFFFAOYSA-N

설명

일반 설명

Triisopropylsilanethiol compound (TIPS-SH) is an organosilicon compound. It is an effective alternative to H2S to prepare unsymmetrical dialkyl sulfides and alkanethiols. During radical reactions, it serves as a polarity reversal catalyst. Furthermore, it serves as a ligand in the Ziegler-Natta polymerization of ethylene. HSTIPS reagent used to prepare 9-BBN-derived alkyl and aryl boranes.

안전성 정보

• 픽토그램: GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H315,H319,H335
• 예방조치 성명서: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 표적 기관: Respiratory system
• Storage Class Code: 10 - Combustible liquids
• WGK: WGK 3
• Flash Point (°F): 170.6 °F - closed cup
• Flash Point (°C): 77 °C - closed cup
• 개인 보호 장비: Eyeshields, Gloves, type ABEK (EN14387) respirator filter