추천 제품
동위원소 순도
99 atom % D
분석
99% (CP)
형태
liquid
기술
NMR: suitable
refractive index
n20/D 1.431 (lit.)
bp
36.5 °C (lit.)
density
0.928 g/mL at 25 °C (lit.)
질량 이동
M+6
SMILES string
[2H]C([2H])([2H])SC([2H])([2H])[2H]
InChI
1S/C2H6S/c1-3-2/h1-2H3/i1D3,2D3
InChI key
QMMFVYPAHWMCMS-WFGJKAKNSA-N
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일반 설명
Dimethyl sulfide-d6 [(CD3)2S] is a deuterated NMR solvent useful in NMR-based research and analyses. It can form 1:1 complex with halothane by the formation of C–H…S hydrogen bonds. During the reaction of (CD3)2S with singlet oxygen in aprotic solvents, the H-D exchange in the methyl group was observed. The electronic spectra of (CD3)2S has been measured between 1250 and 2500Å.
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신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Flam. Liq. 2
Storage Class Code
3 - Flammable liquids
WGK
WGK 1
Flash Point (°F)
-34.6 °F - closed cup
Flash Point (°C)
-37 °C - closed cup
Vibrational spectra of (CH3)2S, CH3SCD3, and (CD3)2S.
Ypenburg JW and Gerding H.
Rec. Trav. Chim., 90(8), 885-895 (1971)
Mechanism of sulfone formation in the reaction of sulfides and singlet oxygen: intermediacy of S-hydroperoxysulfonium ylide.
Ishiguro K, et al.
Journal of the American Chemical Society, 118(31), 7265-7271 (1996)
Intramolecular potential function and methyl-methyl coupling of crystalline dimethyl sulfide.
Levin IW, et al.
Spectrochimica Acta Part A: Molecular Spectroscopy, 31(1), 41-55 (1975)
Assignments of Rydberg and valence transitions in the electronic absorption spectrum of dimethyl sulfide.
McDiarmid R.
J. Chem. Phys., 61(1), 274-281 (1974)
C-H?X (X= S, P) hydrogen bonding: The complexes of halothane with dimethyl sulfide and trimethylphosphine.
Michielsen B, et al.
Journal of Molecular Structure, 1023, 90-95 (2012)
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