모든 사진(1)

주요 문서

모든 문서 보기

405965

2,2′-Methylenebis[(4S)-4-tert-butyl-2-oxazoline]

Name: 2,2′-Methylenebis[(4<I>S</I>)-4-<I>tert</I>-butyl-2-oxazoline]
Brand: ALDRICH

99%

동의어(들):

(S,S)-2,2′-Methylenebis(4-tert-butyl-2-oxazoline)

로그인조직 및 계약 가격 보기

모든 사진(1)

About This Item

실험식(Hill 표기법):

C₁₅H₂₆N₂O₂

CAS Number:

132098-54-5

Molecular Weight:

266.38

Beilstein:

4190673

MDL number:

MFCD00192290

UNSPSC 코드:

12352005

PubChem Substance ID:

24865343

NACRES:

NA.22

추천 제품

Slide 1 of 10

1 of 10

Sigma-Aldrich

680192

2,2-Bis((4S)-(–)-4-isopropyloxazoline)propane

Sigma-Aldrich

416428

2,2′-Methylenebis[(4S)-4-phenyl-2-oxazoline]

Sigma-Aldrich

405981

2,2′-Methylenebis[(4R,5S)-4,5-diphenyl-2-oxazoline]

Sigma-Aldrich

405973

2,2′-Bis[(4S)-4-benzyl-2-oxazoline]

Sigma-Aldrich

405000

(−)-2,2′-Isopropylidenebis[(4S)-4-phenyl-2-oxazoline]

Sigma-Aldrich

406147

2,2′-Isopropylidenebis[(4S)-4-tert-butyl-2-oxazoline]

Sigma-Aldrich

417068

(4S)-(+)-Phenyl-α-[(4S)-phenyloxazolidin-2-ylidene]-2-oxazoline-2-acetonitrile

Sigma-Aldrich

406961

(+)-2,2′-Isopropylidenebis[(4R)-4-phenyl-2-oxazoline]

Sigma-Aldrich

407151

2,6-Bis[(4S)-(−)-isopropyl-2-oxazolin-2-yl]pyridine

Sigma-Aldrich

650897

(4S,4′S)-(−)-2,2′-(3-Pentylidene)bis(4-isopropyloxazoline)

분석

99%

광학 활성

[α]20/D −118°, c = 0.5 in chloroform

mp

51-53 °C (lit.)

작용기

ether

SMILES string

CC(C)(C)[C@H]1COC(CC2=N[C@H](CO2)C(C)(C)C)=N1

InChI

1S/C15H26N2O2/c1-14(2,3)10-8-18-12(16-10)7-13-17-11(9-19-13)15(4,5)6/h10-11H,7-9H2,1-6H3/t10-,11-/m1/s1

InChI key

WCCCBUXURHZPQL-GHMZBOCLSA-N

애플리케이션

2,2′-Methylenebis[(4S)-4-tert-butyl-2-oxazoline] (BOX ligand) can be used as a C₂ symmetric ligand for enantioselective asymmetric catalysis. It easily forms bidentate coordination complexes due to the strong affinity of the oxazoline nitrogen for various metals.

C₂ symmetric ligand for enantioselective catalysis. Easily forms bidentate coordination complexes due to the strong affinity of the oxazoline nitrogen for various metals.