404926

Vanadium(V) oxytriisopropoxide

• 동의어(들): Triisopropoxyvanadium(V) oxide, VTIP, Vanadium(V) trisisopropoxide oxide
• Linear Formula: OV(OCH(CH₃)₂)₃
• CAS Number: 5588-84-1
• Molecular Weight: 244.20
• EC Number: 226-997-4
• MDL number: MFCD00015017
• UNSPSC 코드: 12352103
• PubChem Substance ID: 24865281
• NACRES: NA.23

속성

• 형태: liquid
• Quality Level: 200
• 구성: V, 20.3-21.4% titration (by potassium permanganate)
• 반응 적합성: core: vanadium; reagent type: catalyst
• refractive index: n20/D 1.479 (lit.)
• bp: 80-82 °C/2 mmHg (lit.)
• density: 1.035 g/mL at 25 °C (lit.)
• SMILES string: CC(C)O[V](=O)(OC(C)C)OC(C)C
• InChI: 1S/3C3H7O.O.V/c3*1-3(2)4;;/h3*3H,1-2H3;;/q3*-1;;+3
• InChI key: DSGGJXAUQHKOGQ-UHFFFAOYSA-N

설명

애플리케이션

Asymmetric Transfer Hydrogenation

Vanadium(V) oxytriisopropoxide is a building block for a series of neutral oxovanadium complexes containing both ethoxide and acetylacetonate ligands the complexes have potential biological relevance as well as uses in catalysis. Vanadium (V) oxytriisopropoxide (VOTP) may be used directly as a V precursor to dope TiO₂ to form a high performance anode for lithium ion batteries.

안전성 정보

• 픽토그램: GHS02,GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H226,H315,H319,H335
• 예방조치 성명서: P210 - P233 - P240 - P241 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
• 표적 기관: Respiratory system
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 3
• Flash Point (°F): 113.0 °F - closed cup
• Flash Point (°C): 45 °C - closed cup
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter