381985

Nysted Reagent

20 wt. % suspension in THF

• 동의어(들): cyclo-Dibromodi-μ-methylene[μ-(tetrahydrofuran)]trizinc
• 실험식(Hill 표기법): C₆H₁₂Br₂OZn₃
• CAS Number: 41114-59-4
• Molecular Weight: 456.14
• MDL number: MFCD00134567
• UNSPSC 코드: 12352005
• PubChem Substance ID: 24863854
• NACRES: NA.22
• 양식: slurry

속성

• 양식: slurry
• Quality Level: 200
• 반응 적합성: reaction type: C-C Bond Formation
• 농도: 20 wt. % suspension in THF
• density: 1.186 g/mL at 25 °C (lit.)
• 작용기: ether
• SMILES string: C1CCOC1.Br[Zn]C[Zn]C[Zn]Br
• InChI: 1S/C4H8O.2CH2.2BrH.3Zn/c1-2-4-5-3-1;;;;;;;/h1-4H2;2*1H2;2*1H;;;/q;;;;;;2*+1/p-2
• InChI key: CCTHTLJWXPUNGT-UHFFFAOYSA-L

설명

애플리케이션

Reactant for:

• Synthesis of amphidinolide T3 using a ring-closing metathesis and asymmetric dihydroxylation strategy
• Methylenation of carbonyl compounds
• Olefination reactions

Useful reagent for the methylenation of ketones and α-ketols.

안전성 정보

• 픽토그램: GHS02,GHS08,GHS07
• 신호어: Danger
• 유해 및 위험 성명서: H225,H319,H335,H336,H351
• 예방조치 성명서: P202 - P210 - P233 - P240 - P305 + P351 + P338 - P308 + P313
• Hazard Classifications: Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
• 표적 기관: Central nervous system, Respiratory system
• 보충제 위험성: EUH019
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 3
• Flash Point (°F): -14.8 °F
• Flash Point (°C): -26 °C