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Merck
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Key Documents

335908

Sigma-Aldrich

Isopropyl chloroformate solution

1.0 M in toluene

동의어(들):

1-Methylethyl chloroformate, 2-Propyl chloroformate, Chloroformic acid isopropyl ester, Isopropoxycarbonyl chloride, Isopropyl carbonochloridate, Isopropyl chlorcarbonate, Isopropyl chlorocarbonate

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About This Item

Linear Formula:
(CH3)2CHOCOCl
CAS Number:
Molecular Weight:
122.55
Beilstein:
506416
MDL number:
UNSPSC 코드:
12352100
PubChem Substance ID:
NACRES:
NA.22

형태

liquid

Quality Level

농도

1.0 M in toluene

density

0.892 g/mL at 25 °C

작용기

chloro

저장 온도

2-8°C

SMILES string

CC(C)OC(Cl)=O

InChI

1S/C4H7ClO2/c1-3(2)7-4(5)6/h3H,1-2H3

InChI key

IVRIRQXJSNCSPQ-UHFFFAOYSA-N

유사한 제품을 찾으십니까? 방문 제품 비교 안내

일반 설명

Specific rates of solvolysis of isopropyl chloroformate in various solvents at 25°C has been reported.

애플리케이션

Isopropyl chloroform was used in the preparation of isopropyl cyclohexane via alkylation of cyclohexene. It was also used in the preparation of 10-isopropyloctadecanoic acid via reaction with oleic acid in the presence of ethylaluminum sesquichloride

신호어

Danger

Hazard Classifications

Acute Tox. 1 Inhalation - Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1B - Skin Sens. 1 - STOT RE 2 - STOT SE 3

표적 기관

Central nervous system

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point (°F)

42.8 °F - closed cup

Flash Point (°C)

6 °C - closed cup

개인 보호 장비

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Malcolm J D'Souza et al.
International journal of molecular sciences, 10(3), 862-879 (2009-04-29)
Specific rates of solvolysis at 25 degrees C for isopropyl chloroformate (1) in 24 solvents of widely varying nucleophilicity and ionizing power, plus literature values for studies in water and formic acid, are reported. Previously published solvolytic rate constants at
Biermann et al.
Angewandte Chemie (International ed. in English), 38(24), 3675-3677 (2000-01-29)
The formal addition of propane to nonactivated double bonds can be achieved with isopropyl chloroformate (2) in the presence of Et(3)Al(2)Cl(3). Thus, a 1:1 mixture of 10-isopropyloctadecanoic acid (3) and the 9-regioisomer is formed from oleic acid (1). The reaction
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