303461

(R)-(+)-β-Citronellol

95%

• 동의어(들): (+)-β-Citronellol, (R)-3,7-Dimethyl-6-octen-1-ol
• Linear Formula: (CH₃)₂C=CHCH₂CH₂CH(CH₃)CH₂CH₂OH
• CAS Number: 1117-61-9
• Molecular Weight: 156.27
• Beilstein: 1721506
• EC Number: 214-250-5
• MDL number: MFCD00063215
• UNSPSC 코드: 12352002
• PubChem Substance ID: 24858125
• NACRES: NA.22

속성

• vapor pressure: ~0.02 mmHg ( 25 °C)
• 분석: 95%
• 형태: liquid
• 광학 활성: [α]19/D +5.3°, neat
• refractive index: n20/D 1.456 (lit.)
• bp: 112-113 °C/12 mmHg (lit.)
• density: 0.857 g/mL at 25 °C (lit.)
• SMILES string: C[C@@H](CCO)CC\C=C(\C)C
• InChI: 1S/C10H20O/c1-9(2)5-4-6-10(3)7-8-11/h5,10-11H,4,6-8H2,1-3H3/t10-/m1/s1
• InChI key: QMVPMAAFGQKVCJ-SNVBAGLBSA-N

설명

애플리케이션

(R)-(+)-β-Citronellol can be used to prepare:

• (R)-(+)-β-citronellyl acetate by treating with vinyl acetate via trans esterification reaction using immobilized Rhizomucor miehei lipase as biocatalyst.
• (R)-(+)-citronellal and (R)-(+)-citronellic acid by the oxidation reaction.
• Citronellol aziridine by treating with 2,2,2-trichloroethoxysulfonamide by intermolecular olefin aziridination.

It can also be used as a starting material for the synthesis of (+)-integerrinecic acid lactone.

(R)-(+)-β-Citronellol can undergo:

• Oxidation to form (R)-(+)-citronellal, an antifungal agent and (R)-(+)-citronellic acid.
• Intermolecular olefin aziridination with 2,2,2-trichloroethoxysulfonamide to form citronellol aziridine for ring-opening reactions.
• Series of reactions to form α2δ-ligands for treating generalized anxiety disorder and insomnia.

안전성 정보

• 픽토그램: GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H315,H319,H335
• 예방조치 성명서: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 표적 기관: Respiratory system
• Storage Class Code: 10 - Combustible liquids
• WGK: WGK 3
• Flash Point (°F): 212.0 °F - closed cup
• Flash Point (°C): 100 °C - closed cup
• 개인 보호 장비: Eyeshields, Gloves, type ABEK (EN14387) respirator filter