282146
(1R)-(−)-10-Camphorsulfonic acid
98%
동의어(들):
(−)-Camphor-10-sulfonic acid, (1R)-(−)-Camphor-10-sulfonic acid, (1R)-Camphor-10-sulfonic acid
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모든 사진(1)
About This Item
실험식(Hill 표기법):
C10H16O4S
CAS Number:
Molecular Weight:
232.30
Beilstein:
2809676
EC Number:
MDL number:
UNSPSC 코드:
12352106
PubChem Substance ID:
NACRES:
NA.22
추천 제품
Quality Level
분석
98%
광학 활성
[α]20/D −21°, c = 2 in H2O
mp
198 °C (dec.) (lit.)
작용기
ketone
sulfonic acid
SMILES string
[H][C@]12CC[C@](CS(O)(=O)=O)(C(=O)C1)C2(C)C
InChI
1S/C10H16O4S/c1-9(2)7-3-4-10(9,8(11)5-7)6-15(12,13)14/h7H,3-6H2,1-2H3,(H,12,13,14)/t7-,10-/m0/s1
InChI key
MIOPJNTWMNEORI-XVKPBYJWSA-N
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일반 설명
(1R)-(−)-10-Camphorsulfonic acid is an HPLC derivatization reagent for UV/Vis detection. It is mainly employed for the resolution of bases.
애플리케이션
(1R)-(−)-10-Camphorsulfonic acid may be used as a chiral building block for the synthesis of pentavalent organo-bismuth derivatives by enantioselective C-arylation. It may be used as a chiral monomer in the enantioselective sensing of chiral amino acids by potentiometric sensors based on optical active polyaniline films.
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
(+)-(2R, 8aS)-10-(Camphorylsulfonyl) Oxaziridine.
Towson JC, et al
Organic Syntheses, 158-158 (1993)
Synthesis and reactivity of chiral pentavalent bismuth derivatives
Finet PJ and Fedorov YA
Russian Chemical Bulletin, 53(7), 1488-1495 (2004)
Chen Liu et al.
Organic letters, 13(10), 2638-2641 (2011-04-23)
A novel ion pair catalyst containing a chiral counteranion can be readily derived by simply mixing cinchona alkaloid-derived diamine with chiral camphorsulfonic acid (CSA). A mixture of 9-amino(9-deoxy)epi-quinine 8 and (-)-CSA was found to be the best catalyst with matching
Bala Kishan Gorityala et al.
Bioorganic & medicinal chemistry letters, 19(11), 3093-3095 (2009-04-29)
A mild and efficient synthesis of pseudoglycosides has been developed using metal free (S)-camphorsulfonic acid. (S)-CSA acts as an excellent catalyst for conversion of 2,4,6-tri-O-acetyl-D-glucal to 2,3-unsaturated O-glycosides. A wide range of biologically active natural products, alcohols and thiols could
[D-camphor-beta-sulfonic acid as an ion-pair reagent for the determination of biogenic amines and their metabolites in the rat brain by reverse phase high performance liquid chromatography].
X R Xu et al.
Zhongguo yao li xue bao = Acta pharmacologica Sinica, 8(2), 113-117 (1987-03-01)
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