225754

Allylmagnesium bromide solution

1.0 M in diethyl ether

• 동의어(들): (Prop-2-en-1-yl)magnesium bromide, 2-Propenylmagnesium bromide, Allyl magnesium bromide, Allylbromomagnesium, Allylmagnesiumbromide, Bromo-2-propenylmagnesium
• Linear Formula: CH₂=CHCH₂MgBr
• CAS Number: 1730-25-2
• Molecular Weight: 145.28
• Beilstein: 969335
• MDL number: MFCD00000044
• UNSPSC 코드: 12352103
• PubChem Substance ID: 24853518
• NACRES: NA.22

속성

• Quality Level: 100
• 반응 적합성: reaction type: Grignard Reaction
• 농도: 1.0 M in diethyl ether
• density: 0.851 g/mL at 25 °C
• SMILES string: Br[Mg]CC=C
• InChI: 1S/C3H5.BrH.Mg/c1-3-2;;/h3H,1-2H2;1H;/q;;+1/p-1
• InChI key: FEMBXICCJNZMMC-UHFFFAOYSA-M

설명

일반 설명

Allylmagnesium bromide solution serves as a selective nucleophile toward aza-aromatic heterocycles.

애플리케이션

Allylmagnesium bromide solution can be used in the Grignard reaction, which is a key step to synthesize:

• 2-(9,10-dihydro-9,10-propanoanthracen-9-yl)-N-methylethanamine (2), a homolog of benzoctamine
• tarchonanthuslactone
• (+)-preussin
• polyhydroxylated quinolizidine alkaloids

포장

View returnable container options.

안전성 정보

• 픽토그램: GHS02,GHS05,GHS07
• 신호어: Danger
• 유해 및 위험 성명서: H224,H260,H302,H314,H336
• 예방조치 성명서: P210 - P231 + P232 - P233 - P280 - P303 + P361 + P353 - P305 + P351 + P338 - P403 + P233
• Hazard Classifications: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 1 - Skin Corr. 1B - STOT SE 3 - Water-react 1
• 표적 기관: Central nervous system
• 보충제 위험성: EUH019
• Storage Class Code: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 1
• Flash Point (°F): -40.0 °F - closed cup
• Flash Point (°C): -40 °C - closed cup
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter