224308
Dilithium tetrachlorocuprate(II) solution
0.1 M in THF
동의어(들):
Copper dilithium tetrachloride, Dilithium tetrachlorocuprate(2-), Lithium Tetrachlorocuprate
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모든 사진(1)
About This Item
Linear Formula:
Li2CuCl4
CAS Number:
Molecular Weight:
219.24
EC Number:
MDL number:
UNSPSC 코드:
12352302
PubChem Substance ID:
NACRES:
NA.23
추천 제품
Grade
for analytical purposes
Quality Level
양식
liquid
반응 적합성
reagent type: catalyst
core: copper
농도
0.1 M in THF
density
0.91 g/mL at 25 °C
SMILES string
[Li+].[Li+].Cl[Cu--](Cl)(Cl)Cl
InChI
1S/4ClH.Cu.2Li/h4*1H;;;/q;;;;+2;2*+1/p-4
InChI key
HCJWWBBBSCXJMS-UHFFFAOYSA-J
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애플리케이션
Catalyst used to couple alkyl halides with alkyl Grignard reagents.
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
표적 기관
Respiratory system
보충제 위험성
Storage Class Code
3 - Flammable liquids
WGK
WGK 2
Flash Point (°F)
1.4 °F - closed cup
Flash Point (°C)
-17 °C - closed cup
개인 보호 장비
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
이미 열람한 고객
K Minamoto et al.
Nucleic acids symposium series, (27)(27), 109-110 (1992-01-01)
The reaction of 1-(2,3-anhydro-5-O-trityl-beta-D-lyxofuranosyl)-2-O-methyluracil (1a) and its thymine analogue (1b) with dilithium tetrahalocuprate (Li2CuX4) revealed excellent to perfect regioselectivity, yielding 2,2'-anhydro-3'-halonucleosides (2a-d), while the same reactions with 2,3-anhydro uracil and thymine nucleosides (4a,b) gave arabinosyl (5a-d) and xylosyl halohydrins (6a-d)
Tetrahedron, 62, 4851-4851 (2006)
Kenji Mori
Bioscience, biotechnology, and biochemistry, 74(3), 595-600 (2010-03-09)
A mixture of the four stereoisomers of 1,7-dimethylnonyl propanoate, the female sex pheromone of the western corn rootworm (Diabrotica virgifera virgifera LeConte), was synthesized in four different ways by employing one of the following four reactions as the key step:
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