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Merck
모든 사진(4)

Key Documents

224294

Sigma-Aldrich

Thiophosphoryl chloride

98%

동의어(들):

Phosphorus sulfochloride, Phosphorus thiochloride

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About This Item

Linear Formula:
PSCl3
CAS Number:
Molecular Weight:
169.40
EC Number:
MDL number:
UNSPSC 코드:
12352100
PubChem Substance ID:
NACRES:
NA.22

분석

98%

형태

liquid

refractive index

n20/D 1.555 (lit.)

bp

125 °C (lit.)

mp

−35 °C (lit.)

solubility

benzene: soluble(lit.)
carbon disulfide: soluble(lit.)
carbon tetrachloride: soluble(lit.)
chloroform: soluble(lit.)

density

1.668 g/mL at 25 °C (lit.)

SMILES string

ClP(Cl)(Cl)=S

InChI

1S/Cl3PS/c1-4(2,3)5

InChI key

WQYSXVGEZYESBR-UHFFFAOYSA-N

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관련 카테고리

애플리케이션

Thiophosphoryl chloride was used in the synthesis of O-ethyl dichlorothiophosphate.

픽토그램

Skull and crossbonesCorrosion

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 1 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

표적 기관

Respiratory system

Storage Class Code

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 2

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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문서 라이브러리 방문

D Coloşi-Esca et al.
Journal of applied toxicology : JAT, 4(5), 230-235 (1984-10-01)
The rat acute oral LD50 value of PSCl3 is 750 mg per kg body weight. A rat 90-day oral feeding study at dose levels of 7.5 mg (P1) and 37.5 mg (P5) per kg resulted in increased body weight gain.
[Hygienic substantiation of the maximum permissible level of phosphorus thiotrichloride in reservoir water].
V M Tomkiv
Gigiena i sanitariia, (11)(11), 68-70 (1988-11-01)
Sarah E Lee et al.
Chembiochem : a European journal of chemical biology, 12(4), 633-640 (2011-02-10)
The elucidation of signalling pathways relies heavily upon the identification of protein kinase substrates. Recent investigations have demonstrated the efficacy of chemical genetics using ATP analogues and modified protein kinases for specific substrate labelling. Here we combine N(6) -(cyclohexyl)ATPγS with
Wen Jun Gui et al.
Analytical biochemistry, 357(1), 9-14 (2006-08-22)
Two haptens of the insecticide triazophos (O,O-diethyl O-[1-phenyl-1H-1,2,4-triazol-3-yl] phosphorothioate) were synthesized by introducing appropriate spacers in the O-ethyl site of the analyte molecular structure. First, thiophosphoryl chloride (PSCl(3)) reacts with methanol at low temperature to give O-ethyl dichlorothiophosphate. After reacting
J T Slama et al.
Analytical biochemistry, 209(1), 143-149 (1993-02-15)
Elemental [35S]sulfur was shown to equilibrate with the sulfur of thiophosphoryl chloride when these materials are heated together. This isotopic exchange reaction is the basis of a convenient, microscale synthesis of high specific activity [35S]PSCl3. [35S]Thiophosphoryl chloride is otherwise not

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