212911

Palladium hydroxide on carbon

extent of labeling: 20 wt. % loading (dry basis), matrix carbon, wet support

• 동의어(들): Pd(OH)₂/C, Pearlman’s catalyst
• 실험식(Hill 표기법): H₂O₂Pd
• CAS Number: 12135-22-7
• Molecular Weight: 140.43
• EC Number: 235-219-2
• MDL number: MFCD00064599
• UNSPSC 코드: 12161600
• PubChem Substance ID: 24852754
• NACRES: NA.22

속성

• 형태: powder
• Quality Level: 200
• 포함: ≤50% water
• 반응 적합성: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst
• 라벨링 범위: 20 wt. % loading (dry basis)
• 기질: carbon, wet support
• SMILES string: O[Pd]O
• InChI: 1S/2H2O.Pd/h2*1H2;/q;;+2/p-2
• InChI key: NXJCBFBQEVOTOW-UHFFFAOYSA-L

설명

애플리케이션

Addition of Pd/C to Pd(OH)₂/C improves the efficiency of N- or O-debenzylation.

Effectively catalyzes the direct arylation reactions of aryl iodides and bromides in both intra- and intermolecular processes.

Particularly active for hydrogenolysis of benzyl-nitrogen bonds, and has proven successful even where other palladium-on-carbon catalysts have failed.

Product can be used with our benchtop hydrogen generator, H-Genie Lite (Z744083)

안전성 정보

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: Eyeshields, Gloves, type N95 (US)