190438

(S)-(−)-2-Amino-3-phenyl-1-propanol

98%, optical purity ee: 99% (HPLC)

• 동의어(들): L-Phenylalaninol
• Linear Formula: C₆H₅CH₂CH(NH₂)CH₂OH
• CAS Number: 3182-95-4
• Molecular Weight: 151.21
• Beilstein: 2208238
• EC Number: 221-674-4
• MDL number: MFCD00004732
• UNSPSC 코드: 12352116
• PubChem Substance ID: 24851436
• NACRES: NA.22

속성

• Quality Level: 100
• 분석: 98%
• 양식: solid
• 광학 활성: [α]22/D −22.8°, c = 1.2 in 1 M HCl
• 광학 순도: ee: 99% (HPLC)
• mp: 92-94 °C (lit.)
• 작용기: amine; hydroxyl; phenyl
• SMILES string: N[C@H](CO)Cc1ccccc1
• InChI: 1S/C9H13NO/c10-9(7-11)6-8-4-2-1-3-5-8/h1-5,9,11H,6-7,10H2/t9-/m0/s1
• InChI key: STVVMTBJNDTZBF-VIFPVBQESA-N

설명

일반 설명

(S)-(-)-2-Amino-3-phenyl-1-propanol is a chiral amino alcohol.

애플리케이션

(S)-(-)-2-Amino-3-phenyl-1-propanol can undergo condensation with 5-nitro­salicylaldehyde to form (S)-2-[(1-benzyl-2-hydroxy­ethyl­imino)meth­yl]-4-nitro­phenol, a new chiral Schiff base. It reacts with substituted salicylaldehydes to form tridentate chiral Schiff base ligands, which can form H-bonded chiral supramolecular metal-organic architectures. It can also be used in the synthesis of an unnatural tripeptide, which can enhance the antimicrobial activity of methicillin against methicillin resistant Staphylococcus aureus.

Reacts with nitriles to form oxazolines which are useful in Pd-catalyzed allylic substitution. Also employed in amidation for chiral resolution and NADH modeling.

안전성 정보

• Storage Class Code: 8A - Combustible corrosive hazardous materials
• WGK: WGK 3
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges