186201
Methyllithium lithium bromide complex solution
1.5 M in diethyl ether
동의어(들):
MeLi·LiBr, Methyllithium complex with lithium bromide, Methyllithium lithium bromide complex (1:1)
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모든 사진(2)
About This Item
Linear Formula:
CH3Li · LiBr
Molecular Weight:
108.82
Beilstein:
3587162
MDL number:
UNSPSC 코드:
12352103
PubChem Substance ID:
NACRES:
NA.22
추천 제품
양식
liquid
Quality Level
농도
1.5 M in diethyl ether
density
0.852 g/mL at 25 °C
저장 온도
2-8°C
SMILES string
[Li+].[Br-].[Li]C
[Li+].[Br-].[Li]C
InChI
1S/CH3.BrH.2Li/h1H3;1H;;/q;;;+1/p-1
1S/CH3.BrH.2Li/h1H3;1H;;/q;;;+1/p-1
InChI key
XLIKYFMMLMHLKL-UHFFFAOYSA-M
XLIKYFMMLMHLKL-UHFFFAOYSA-M
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애플리케이션
Methyllithium lithium bromide complex solution (MeLi.LiBr) can be used as a methylating agent for the α-methylation of alkoxyaryl ketones.
포장
The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.
법적 정보
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 4 Oral - Flam. Liq. 2 - STOT SE 3
표적 기관
Respiratory system
보충제 위험성
Storage Class Code
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 3
Flash Point (°F)
-18.4 °F - closed cup
Flash Point (°C)
-28 °C - closed cup
이미 열람한 고객
Unusual alpha-methylation of alkoxyaryl ketones with higher order methyl cuprate and lithium bromide.
M E Jung et al.
The Journal of organic chemistry, 65(26), 9241-9244 (2001-01-10)
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