179043

Borane N,N-diethylaniline complex

• 동의어(들): (N,N-Diethylaniline)trihydroboron, Diethylphenylamine-borane, NSC 239123
• Linear Formula: C₆H₅N(C₂H₅)₂·BH₃
• CAS Number: 13289-97-9
• Molecular Weight: 163.07
• EC Number: 236-305-2
• MDL number: MFCD00013187
• UNSPSC 코드: 12352116
• PubChem Substance ID: 24850794
• NACRES: NA.22

속성

• 형태: liquid
• Quality Level: 200
• 반응 적합성: reagent type: reductant
• mp: −30-−27 °C (lit.)
• density: 0.917 g/mL at 25 °C (lit.)
• SMILES string: B.CCN(CC)c1ccccc1
• InChI: 1S/C10H15N.BH3/c1-3-11(4-2)10-8-6-5-7-9-10;/h5-9H,3-4H2,1-2H3;1H3
• InChI key: YPWBYWNNJVSNPQ-UHFFFAOYSA-N

설명

애플리케이션

Reactant for:

• Diastereoselective reduction of prochiral enone intermediates
• Borylation of aryl halides
• Reductions of ketones, acids, esters, amides, and nitriles
• Investigations of borane source on enantioselectivity in enantiopure oxazaborolidine-catalyzed asymmetric borane reduction of ketones

Reactant for synthesis of:

• Chromanol derivatives as CETP inhibitors for the treatment of cardiovascular disease
• Allylic alcohols via enantioselective reductions
• Pinacolboranes for one-pot synthesis of unsymmetrical biaryls

안전성 정보

• 픽토그램: GHS02
• 신호어: Danger
• 유해 및 위험 성명서: H225,H261
• 예방조치 성명서: P210 - P223 - P231 + P232 - P233 - P240 - P241
• Hazard Classifications: Flam. Liq. 2 - Water-react 2
• 보충제 위험성: EUH014
• Storage Class Code: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 3
• Flash Point (°F): 69.8 °F - closed cup
• Flash Point (°C): 21 °C - closed cup
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter