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Merck
모든 사진(4)

Key Documents

177261

Sigma-Aldrich

DPPF

greener alternative

97%

동의어(들):

1,1′-Ferrocenediyl-bis(diphenylphosphine), dppf

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About This Item

실험식(Hill 표기법):
C34H28FeP2
CAS Number:
Molecular Weight:
554.38
MDL number:
UNSPSC 코드:
12350000
PubChem Substance ID:
NACRES:
NA.22

Quality Level

분석

97%

형태

powder

반응 적합성

reaction type: Cross Couplings
reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction

reagent type: ligand
reaction type: Carbonylations

reagent type: ligand
reaction type: Ene Reaction

reagent type: ligand
reaction type: Heck Reaction

reagent type: ligand
reaction type: Negishi Coupling

reagent type: ligand
reaction type: Sonogashira Coupling

reagent type: ligand
reaction type: Stille Coupling

reagent type: ligand
reaction type: Suzuki-Miyaura Coupling

reagent type: ligand
reaction type: Tsuji-Trost Reaction

환경친화적 대안 제품 특성

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

181-182 °C (dec.) (lit.)

작용기

phosphine

환경친화적 대안 카테고리

SMILES string

[Fe].[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.[CH]4[CH][CH][C]([CH]4)P(c5ccccc5)c6ccccc6

InChI

1S/2C17H14P.Fe/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;/h2*1-14H;

InChI key

HPXNTHKXCYMIJL-UHFFFAOYSA-N

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일반 설명

Novel functionalized furan derivatives were prepared via Pd-phosphine sequential C-C and C-O bond formation.
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애플리케이션

Ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing.

Ruthenium-Catalyzed N-Alkylation of Amines and Sulfonamides Using Borrowing Hydrogen Methodology
Ligand used in a Pd(II)-catalyzed cross-coupling synthesis of oxazepine ring systems.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

Eyeshields, Gloves, type N95 (US)


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시험 성적서(COA)

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문서 라이브러리에서 최근에 구매한 제품에 대한 문서를 찾아보세요.

문서 라이브러리 방문

Tanimori, Shinji; et al.
Synthesis, 5, 865-869 (2006)
Wolfe, J. P.; Buchwald, S. L.
Journal of the American Chemical Society, 119, 6054-6054 (1997)
Anastasia, L.; Dumond, Y. R.; Negishi, E.
European Journal of Organic Chemistry, 3039-3039 (2001)
Alejandro Pérez Luna et al.
Organic letters, 5(25), 4771-4774 (2003-12-05)
The diastereoselective synthesis of hydrazinocyclopentenes 6 or 7 can be achieved in a straightforward manner from Diels-Alder adduct 4 using an acid-catalyzed rearrangement or a palladium-catalyzed allylic substitution reaction. In the latter case, enantioenriched compounds with ee values up to
Lera et al.
Organic letters, 2(24), 3873-3875 (2000-12-02)
A method for the palladium-catalyzed synthesis of alkynylphosphonates from 1,1-dibromo-1-alkenes has been developed. In general, the best catalyst system for this transformation was found to be Pd(OAc)(2), dppf, H-phosphonate, propylene oxide, DMF, 80 degrees C. The reaction appears tolerant of

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