추천 제품
vapor density
1 (vs air)
Quality Level
vapor pressure
9.75 psi ( 20 °C)
분석
99%
양식
liquid
expl. lim.
70 %
bp
32-34 °C (lit.)
density
1.342 g/mL at 25 °C (lit.)
저장 온도
2-8°C
SMILES string
Cl[SiH](Cl)Cl
InChI
1S/Cl3HSi/c1-4(2)3/h4H
InChI key
ZDHXKXAHOVTTAH-UHFFFAOYSA-N
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일반 설명
Trichlorosilane is used as a reducing agent in certain chemical reactions or as a starting material for the synthesis of various organosilicon compounds. Trichlorosilane is generally used for the asymmetric hydrosilylation of olefins in the presence of palladium catalysts coordinated with chiral monodentate phosphorus ligands to generate chiral organosilanes.
애플리케이션
Trichlorosilane has been used to synthesize 11-dicyclohexylphosphino-12-phenyl-9,10-dihydro-9,10-ethenoanthracene (H-KITPHOS) via reduction of 11-dicyclohexylphosphinoyl-12-phenyl-9,10-dihydro-9,10-ethenoanthracene.
Other possible applications:
L-valine-derived catalyst to form secondary amines.
derivatives is an effective reagent for the reduction of imines to form
enantiomerically enriched amines.
Other possible applications:
- Asymmetric reduction of N-aryl ketimines in the presence of a novel
L-valine-derived catalyst to form secondary amines.
- Hydrosilylation of imidazolinones to form chiral imidazolidinones in the presence of a 2,2′-bispyrrolidine based Lewis base organocatalyst.
- Trichlorosilane activated with chiral N-formylproline
derivatives is an effective reagent for the reduction of imines to form
enantiomerically enriched amines.
- Trichlorosilane reacts with dimethylformamide to form hypervalent hydridosilicates, which can reduce aldehydes to alcohols, imines to amines, and also for the reductive amination of aldehydes.
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 1 - Skin Corr. 1A - Water-react 1
보충제 위험성
Storage Class Code
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 1
Flash Point (°F)
<-2.2 °F - Equilibrium method
Flash Point (°C)
< -19 °C - Equilibrium method
개인 보호 장비
Faceshields, Gloves, Goggles
이미 열람한 고객
First chemo-and stereoselective reduction of imines using trichlorosilane activated with N-formylpyrrolidine derivatives
Iwasaki F
Tetrahedron Letters, 42(13), 2525-2527 (2001)
Trinh Lam et al.
Scientific reports, 7(1), 1188-1188 (2017-04-28)
A chemically patterned microfluidic paper-based analytical device (C-µPAD) is developed to create fluidic networks by forming hydrophobic barriers using chemical vapor deposition (CVD) of trichlorosilane (TCS) on a chromatography paper. By controlling temperature, pattern size, and CVD duration, optimal conditions
Naama Peor et al.
Journal of the American Chemical Society, 130(12), 4158-4165 (2008-03-05)
Electronic structures at the Si/SiO2/molecule interfaces were studied by Kelvin probe techniques (contact potential difference) and compared to theoretical values derived by the Helmholtz equation. Two parameters influencing the electronic properties of n-type <100> Si/SiO2 substrates were systematically tuned: the
Hyundong Yoo et al.
Scientific reports, 8(1), 6904-6904 (2018-05-04)
Silicon (Si) based materials are highly desirable to replace currently used graphite anode for lithium ion batteries. Nevertheless, its usage is still a big challenge due to poor battery performance and scale-up issue. In addition, two-dimensional (2D) architectures, which remain
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