추천 제품
분석
99%
bp
−22.5 °C (lit.)
mp
<−78 °C (lit.)
작용기
fluoro
iodo
SMILES string
FC(F)(F)I
InChI
1S/CF3I/c2-1(3,4)5
InChI key
VPAYJEUHKVESSD-UHFFFAOYSA-N
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애플리케이션
Reagent used in the rhodium-catalyzed α-trifluoromethylation of α,ß-unsaturated ketones.
포장
Supplied in a Sure/Pac™ cylinder and has a brass needle valve with a male 1/4" NPTF outlet thread installed. Before using the cylinder, ensure that the valve is closed, then remove the galvanized steel hex cap that seals the outlet valve.
Compatible with the following:
Compatible with the following:
법적 정보
Aldrich is a registered trademark of Sigma-Aldrich Co. LLC
Sure/Pac is a trademark of Sigma-Aldrich Co. LLC
또한 이 제품과 함께 일반적으로 구입
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설명
가격
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Warning
유해 및 위험 성명서
Hazard Classifications
Muta. 2 - Ozone 1 - Press. Gas Compr. Gas
Storage Class Code
2A - Gases
WGK
WGK 1
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
Eyeshields, Gloves
D E Dodd et al.
Inhalation toxicology, 11(11), 1041-1055 (1999-11-24)
CF(3)I is being considered by the U.S. Air Force as a replacement for Halon 1301 for fire-extinguishing requirements in unoccupied spaces. The purpose of this study was to determine and evaluate the potential for CF(3)I to produce reproductive toxicity and
C Stefan Lehmann et al.
Faraday discussions, 153, 173-187 (2011-01-01)
The control of multichannel ionic fragmentation dynamics in CF3I is studied by femtosecond pulse shaping and velocity map photoelectron photoion coincidence imaging. When CF3I is photoexcited with femtosecond laser pulses around 540 nm there are two major ions observed in
G Hancock et al.
Physical chemistry chemical physics : PCCP, 9(18), 2234-2239 (2007-05-10)
Frequency modulated diode laser based absorption at 1.315 microm has been used to measure the Doppler lineshapes of the I((2)P(1/2)-(2)P(3/2)) transition in atomic iodine produced from the 266 nm photolysis of both CF(3)I and C(2)F(5)I. Wavelength resolved laser gain is
A Vinegar et al.
Inhalation toxicology, 12(8), 751-763 (2000-07-06)
Most proposed replacements for Halon 1301 as a fire suppressant are halogenated hydrocarbons. The acute toxic endpoint of concern for these agents is cardiac sensitization. An approach is described that links the cardiac endpoint as assessed in dogs to a
Natalia B Shustova et al.
Journal of the American Chemical Society, 128(49), 15793-15798 (2006-12-07)
Reaction of a mixture of insoluble higher fullerenes with CF3I at 500 degrees C produced a single abundant isomer of C74(CF3)12, C76(CF3)12, and C80(CF3)12, two abundant isomers of C78(CF3)12 and C82(CF3)12, and an indeterminant number of isomers of C84(CF3)12. Using
문서
In 2001, Professor William Dolbier, Jr., at the University of Florida reported1 an approach to nucleophilic trifluoromethylation based on the generation of a trifluoromethyl anion using CF3I in the presence of a powerful twoelectron reductant, tetrakis(dimethylamino)ethylene (TDAE)
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