142875
2,6-Pyridinedicarbonyl dichloride
97%
동의어(들):
2,6-Pyridinedicarbonyl chloride, Pyridine-2,6-dicarboxylic acid chloride
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모든 사진(2)
About This Item
실험식(Hill 표기법):
C7H3Cl2NO2
CAS Number:
Molecular Weight:
204.01
Beilstein:
131556
EC Number:
MDL number:
UNSPSC 코드:
12352100
PubChem Substance ID:
NACRES:
NA.22
추천 제품
Quality Level
분석
97%
양식
solid
bp
284 °C (lit.)
mp
56-58 °C (lit.)
작용기
acyl chloride
SMILES string
ClC(=O)c1cccc(n1)C(Cl)=O
InChI
1S/C7H3Cl2NO2/c8-6(11)4-2-1-3-5(10-4)7(9)12/h1-3H
InChI key
GWHOGODUVLQCEB-UHFFFAOYSA-N
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애플리케이션
2,6-Pyridinedicarbonyl dichloride can be used as a starting material to synthesize:
- Pyridine-based polyamido-polyester optically active macrocycles by reacting with chiral diamine dihydrobromides.
- Pyridine-bridged 2,6-bis-carboxamide Schiff′s bases by treating with L-alanine or 2-methyl-alanine methyl esters.
- N,N′-bis(1-pyrenylmethyl)pyridine-2,6-dicarboxamide by reacting with 1-pyrenemethylamine hydrochloride in the presence of a base.
신호어
Warning
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Skin Sens. 1A
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
개인 보호 장비
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
이미 열람한 고객
H Zhao et al.
The Journal of organic chemistry, 65(10), 2933-2938 (2000-05-18)
Five new chiral macrocycles, 3a-e, have been prepared by the acylation cyclization of chiral diamine dihydrobromide intermediates 2a-c with 2,6-pyridinedicarbonyl dichloride in highly diluted solution at room temperature. The chiral diesters 1a-c needed for the preparation of the macrocycles were
Mohamed A Al-Omar et al.
Molecules (Basel, Switzerland), 15(7), 4711-4721 (2010-07-27)
A series of pyridine-bridged 2,6-bis-carboxamide Schiff's bases has been prepared starting from 2,6-pyridinedicarbonyl dichloride (1) and L-alanine or 2-methyl-alanine methyl ester.The coupling of acid chloride 1 with L-alanine methyl ester hydrochloride -or 2-methylalanine methyl ester hydrochloride gave the corresponding 2,6-bis-carboxamide
Synthesis of some new pyridine-2, 6-carboxamide-derived Schiff bases as potential antimicrobial agents
Al-Omar MA and Amr Abd El-Galil E
Molecules (Basel), 15(7), 4711-4721 (2010)
Howard M Colquhoun et al.
Faraday discussions, 143, 205-220 (2009-01-01)
A novel type of tweezer molecule containing electron-rich 2-pyrenyloxy arms has been designed to exploit intramolecular hydrogen bonding in stabilising a preferred conformation for supramolecular complexation to complementary sequences in aromatic copolyimides. This tweezer-conformation is demonstrated by single-crystal X-ray analyses
Global Trade Item Number
SKU | GTIN |
---|---|
532754-25G | 4061832100647 |
142875-5G | 4061838734525 |
142875-1G | |
142875-25G | 4061838734518 |
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