- Nickel-catalyzed sonogashira reactions of non-activated secondary alkyl bromides and iodides.
Nickel-catalyzed sonogashira reactions of non-activated secondary alkyl bromides and iodides.
Angewandte Chemie (International ed. in English) (2013-10-12)
Jun Yi, Xi Lu, Yan-Yan Sun, Bin Xiao, Lei Liu
PMID24115611
要旨
A nicked reaction: The title reaction of terminal alkynes with non-activated secondary alkyl iodides and bromides was accomplished for the first time. This reaction provides a new and practical approach for the synthesis of substituted alkynes (see scheme; cod=cyclo-1,5-octadiene).
材料