- Reusable and environmentally friendly ionic trinuclear iron complex catalyst for atom transfer radical polymerization.
Reusable and environmentally friendly ionic trinuclear iron complex catalyst for atom transfer radical polymerization.
Chemical communications (Cambridge, England) (2007-05-04)
Shota Niibayashi, Hitoshi Hayakawa, Ren-Hua Jin, Hideo Nagashima
PMID17476410
要旨
Ionic iron complex [(Me(3)tacn)(2)Fe(2)Cl(3)](+)[(Me(3)tacn)FeCl(3)](-) (1), which is readily soluble in methanol, acted as a powerful catalyst in controlled radical polymerization of styrene and MMA, and showed promising features of removal from the resulting polymers and was reusable after recovery from the crude products.
材料