- Palladium-catalyzed aminosulfonylation of aryl halides.
Palladium-catalyzed aminosulfonylation of aryl halides.
Journal of the American Chemical Society (2010-10-30)
Bao Nguyen, Edward J Emmett, Michael C Willis
PMID21028814
要旨
The palladium-catalyzed three-component coupling of aryl iodides, sulfur dioxide, and hydrazines to deliver aryl N-aminosulfonamides is described. The colorless crystalline solid DABCO·(SO(2))(2) was used as a convenient source of sulfur dioxide. The reaction tolerates significant variation of both the aryl iodide and hydrazine coupling partners.
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