コンテンツへスキップ
Merck

Polycyclic aromatic triptycenes: oxygen substitution cyclization strategies.

Journal of the American Chemical Society (2012-04-19)
Brett VanVeller, Derek J Schipper, Timothy M Swager
要旨

The cyclization and planarization of polycyclic aromatic hydrocarbons with concomitant oxygen substitution was achieved through acid catalyzed transetherification and oxygen-radical reactions. The triptycene scaffold enforces proximity of the alcohol and arene reacting partners and confers significant rigidity to the resulting π-system, expanding the tool set of iptycenes for materials applications.

材料
製品番号
ブランド
製品内容

Sigma-Aldrich
2-チエニルボロン酸, ≥95.0%