8.18287

Lithium iodide

anhydrous for synthesis

• 別名: Lithium iodide
• 実験式（ヒル表記法）: ILi
• CAS番号: 10377-51-2
• 分子量: 133.85
• MDL番号: MFCD00011092
• UNSPSCコード: 12352302
• EC Index Number: 233-822-5
• NACRES: NA.22

特性

• 品質水準: 200
• 形状: powder
• mp: 450 °C
• 溶解性: soluble 1640 g/L
• 密度: 4 g/cm³ at 20 °C
• かさ密度: 1000 kg/m³
• 保管温度: 2-30°C
• InChI: 1S/HI.Li/h1H;/q;+1/p-1
• InChI Key: HSZCZNFXUDYRKD-UHFFFAOYSA-M

詳細

アプリケーション

Lithium iodide (LiI) can be used as a catalyst to synthesize:

• N-alkyl 2-pyridone derivatives via O- to N-[1,3]-alkyl migration.
• β-mannosides and β-rhamnosides from glycosyl hemiacetals via one-pot chlorination, iodination, and glycosylation reaction.

It can also be used as:

• Solid electrolyte in the synthesis of Vycor glass/LiI composites applicable in the development of solid-state batteries.
• Iodine source to synthesize primary, secondary, and bridgehead tertiary alkyl iodides by PPh₃-catalyzed iododecarboxylation of aliphatic carboxylates.

アナリシスノート

Assay (argentometric): ≥ 98.0 %
Water (K. F.): ≤ 0.50 %

安全性情報

• 保管分類コード: 13 - Non Combustible Solids
• WGK: WGK 1
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable