8.01647

Boron trifluoride-diethyl ether complex

for synthesis

• 別名: Boron trifluoride-diethyl ether complex, Boron trifluoride-ethyl etherate
• 実験式（ヒル表記法）: C₄H₁₀O · BF₃
• CAS番号: 109-63-7
• 分子量: 141.93
• MDL番号: MFCD00013194
• UNSPSCコード: 12352301
• EC Index Number: 203-689-8
• NACRES: NA.22

特性

• グレード: for synthesis; synthesis grade
• 品質水準: 200
• 蒸気圧: 2.35 hPa ( 20 °C)
• フォーム: liquid
• 自己発火温度: 185 °C (DIN 51794)
• expl. lim.: 5.1-18.2 % (v/v)
• 動粘度: 1.69 cSt(20 °C)
• mp: -58 °C
• 転移温度: flash point 58.5 °C (DIN 51758)
• 密度: 1.13 g/cm³ at 20 °C
• 保管温度: 2-30°C
• SMILES記法: B(F)(F)F.O(CC)CC
• InChI: 1S/C4H10O.BF3/c1-3-5-4-2;2-1(3)4/h3-4H2,1-2H3;
• InChI Key: KZMGYPLQYOPHEL-UHFFFAOYSA-N

詳細

アプリケーション

• Synthesis of a new boron complex with imine ligand: Synthesis, characterization and fluorescent properties: This article discusses the synthesis and properties of a novel boron complex with imine ligand, highlighting its fluorescent characteristics (Şen, 2019).
• Facile synthesis of diphenylmethyl esters from 2-diphenylmethoxypyridine using catalytic boron trifluoride· diethyl etherate: A method for synthesizing diphenylmethyl esters employing boron trifluoride· diethyl etherate as a catalyst is presented (La and Kim, 2018).
• An impedance-morphology study on poly (3-methylthiophene) coated electrode obtained in boron trifluoride diethyl etherate–acetonitrile: This research examines the effects of boron trifluoride diethyl etherate on the impedance and morphology of polythiophene coatings (Dolas and Sarac, 2014).
• A fast and practical synthesis of tert-butyl esters from 2-tert-butoxypyridine using boron trifluoride· diethyl etherate under mild conditions: The article details a synthesis technique for tert-butyl esters using boron trifluoride· diethyl etherate, emphasizing its efficiency and mild reaction conditions (La and Kim, 2018).

アナリシスノート

Assay BF3 (acidimetric): 48.0 - 52.0 %
Density (d 20 °C/ 4 °C): 1.120 - 1.130

安全性情報

• ピクトグラム: GHS02,GHS08,GHS05,GHS07
• シグナルワード: Danger
• 危険有害性情報: H226,H302 + H332,H314,H372
• 注意書き: P210 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P314
• 危険有害性の分類: Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT RE 1 Inhalation
• ターゲットの組織: Kidney
• 保管分類コード: 3 - Flammable liquids
• WGK: WGK 1
• 引火点(°F): 137.3 °F - closed cup
• 引火点(℃): 58.5 °C - closed cup