931845

GenOx-PJ

• 別名: 3-Oxo-2-tosyl-2,3-dihydro-1H-1λ₃-benzo[d][1,2]iodazol-1-yl acetate
• 実験式（ヒル表記法）: C₁₆H₁₄INO₅S
• CAS番号: 2243393-44-2
• 分子量: 459.26
• UNSPSCコード: 12352200
• NACRES: NA.21

特性

• 形状: powder
• 品質水準: 100
• mp: >300 °C
• 官能基: iodo
• 保管温度: −20°C

詳細

アプリケーション

GenOx-PJ is an iodine(III) based oxidant developed by Genentech as part of a robust method of forming C-O bonds through direct coupling of carboxylic acids with alcohols. When used with a Ru(II) photocatalyst, GenOx-PJ is active in the decarboxylative coupling of a broad range of carboxylic acids--including primary, secondary, tertiary, as well as peptides--with alcohols. By this method, GenOx-PJ enables a direct approach in utilizing simple, readily available substrates to perform this type of coupling, and providing many synthetic applications.

その他情報

A Platform for Decarboxylative Couplings via Photoredox Catalysis: Direct Access to Carbocations from Carboxylic Acids for Carbon−Oxygen Bond Formation

安全性情報

• 保管分類コード: 11 - Combustible Solids
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable