930059

S-Phenyl methanethioate

• 別名: Phenyl thioCORMate, Phenyl thioformate
• 実験式（ヒル表記法）: C₇H₆OS
• CAS番号: 27064-03-5
• 分子量: 138.19
• MDL番号: MFCD32756471
• UNSPSCコード: 12352101
• NACRES: NA.06

特性

• 形状: liquid
• 品質水準: 100
• 屈折率: n/D 1.586
• 密度: 1.134 g/mL
• 官能基: thioether
• 保管温度: −20°C
• SMILES記法: [H]C(SC1=CC=CC=C1)=O

詳細

アプリケーション

S-phenyl methanethioate is an effective CO releasing molecule (CORM) developed by the lab of Sarah Tasker as part of a series of thioformate based CORMs called thioCORMates. p-NO₂ phenyl thioformate generates CO over the course of several minutes to allow for on-demand generation of CO for variety of reactions.

This and the other thioCORMates are cost effective CORMs that when activated with simple amines, can be used to generate a near quantitative amount of CO safely without the usage of gas cylinders. These are compatible with a variety of carbonylation reactions, as well as existing COware glassware and components.

ThioCORMate: Tunable and Cost-Effective Carbon Monoxide-Releasing Molecule

Learn more about CO releasing molecules from Prof. Skrydstrup

安全性情報

• ピクトグラム: GHS07
• シグナルワード: Warning
• 危険有害性情報: H315,H319,H335
• 注意書き: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• 危険有害性の分類: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• ターゲットの組織: Respiratory system
• 保管分類コード: 10 - Combustible liquids
• WGK: WGK 3
• 引火点(°F): 221.0 °F
• 引火点(℃): 105 °C