798835

[Ru(phd)₃](PF₆)₂

• 別名: Tris(1,10-phenanthroline-5,6-dione)ruthenium(II) bis(hexafluorophosphate)
• 実験式（ヒル表記法）: C₃₆H₁₈F₁₂N₆O₆P₂Ru
• CAS番号: 184023-77-6
• 分子量: 1021.56
• UNSPSCコード: 12352202
• PubChem Substance ID: 329768673
• NACRES: NA.22

特性

• 形状: powder
• 反応適合性: core: ruthenium; reagent type: catalyst
• SMILES記法: F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.O=C1C2=C(C3=NC=CC=C3C1=O)N=CC=C2.O=C4C(C=CC=N5)=C5C6=C(C4=O)C=CC=N6.O=C7C8=CC=CN=C8C9=C(C7=O)C=CC=N9.[Ru+2]
• InChI: 1S/3C12H6N2O2.2F6P.Ru/c3*15-11-7-3-1-5-13-9(7)10-8(12(11)16)4-2-6-14-10;2*1-7(2,3,4,5)6;/h3*1-6H;;;/q;;;2*-1;+2
• InChI Key: LGAOGZFZNIEFHF-UHFFFAOYSA-N

詳細

アプリケーション

In combination with Co(salophen), (Aldrich 345652), [Ru(phd)₃](PF₆)₂ is utilized in the aerobic oxidation of tetrahydroquinolines at room temperature to form quinolines. Unlike previous catalyst systems, the reported application is highly efficient under the presence of atmospheric oxygen.

法的情報

Modular o-Quinone Catalyst System for Dehydrogenation of Tetrahydroquinolines under Ambient Conditions

安全性情報

• 保管分類コード: 13 - Non Combustible Solids
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable