681482

2-(Allyldimethylsilyl)pyridine

90%

• 別名: Allyldimethyl(2-pyridyl)silane
• 化学式: (CH₂CHCH₂)Si(CH₃)₂(C₅H₄N)
• CAS番号: 118722-54-6
• 分子量: 177.32
• MDL番号: MFCD09265157
• UNSPSCコード: 12352103
• PubChem Substance ID: 24885637
• NACRES: NA.22

特性

• アッセイ: 90%
• 屈折率: n20/D 1.5046
• 密度: 0.913 g/mL at 25 °C
• 保管温度: 2-8°C
• SMILES記法: C[Si](C)(CC=C)c1ccccn1
• InChI: 1S/C10H15NSi/c1-4-9-12(2,3)10-7-5-6-8-11-10/h4-8H,1,9H2,2-3H3
• InChI Key: WIRIPVDRZYVTCG-UHFFFAOYSA-N

詳細

アプリケーション

2-(Allyldimethylsilyl)pyridine can be used as a pyridyl transfer reagent to prepare substituted pyridine derivatives by reacting with various aryl iodides in the presence of a palladium catalyst and silver(I) oxide activator. It can also be utilized as a coupling reagent in the allylation of carbonyl compounds using a copper catalyst.

安全性情報

• ピクトグラム: GHS07
• シグナルワード: Warning
• 危険有害性情報: H315,H319,H335
• 注意書き: P261 - P305 + P351 + P338
• 危険有害性の分類: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 保管分類コード: 10 - Combustible liquids
• WGK: WGK 3
• 引火点(°F): 160.0 °F - closed cup
• 引火点(℃): 71.1 °C - closed cup
• 個人用保護具 (PPE): Eyeshields, Gloves, type ABEK (EN14387) respirator filter