422150

トリフェニルシランチオール

98%

• 別名: メルカプトトリフェニルシラン
• 化学式: (C₆H₅)₃SiSH
• CAS番号: 14606-42-9
• 分子量: 292.47
• Beilstein: 2941369
• MDL番号: MFCD00192551
• UNSPSCコード: 12352103
• PubChem Substance ID: 24866296
• NACRES: NA.22

特性

• アッセイ: 98%
• mp: 101-104 °C (lit.)
• SMILES記法: S[Si](c1ccccc1)(c2ccccc2)c3ccccc3
• InChI: 1S/C18H16SSi/c19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15,19H
• InChI Key: MQDRKELSDPESDZ-UHFFFAOYSA-N

詳細

詳細

Triphenylsilanethiol, also known as triphenylsilyl mercaptan, is an organosilicon compound that is commonly used as a reagent in organic synthesis. It can be used as a reagent for palladium-catalyzed cross-coupling reactions, such as the Stille coupling and the Sonogashira coupling reactions.

アプリケーション

Triphenylsilanethiol can be used as:      

• A reactant to synthesis β-hydroxymercaptans or β-dihydroxysulfides by ring opening of epoxides.      
• An additive in the selective C–H bond functionalization of widely available trialkylamine scaffolds.

安全性情報

• 保管分類コード: 11 - Combustible Solids
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable
• 個人用保護具 (PPE): Eyeshields, Gloves, type N95 (US)