343870

1-Bromo-3-(trifluoromethoxy)benzene

99%

• 化学式: BrC₆H₄OCF₃
• CAS番号: 2252-44-0
• 分子量: 241.01
• MDL番号: MFCD00040943
• UNSPSCコード: 12352100
• PubChem Substance ID: 24861214
• NACRES: NA.22

特性

• 品質水準: 100
• アッセイ: 99%
• 形状: liquid
• 屈折率: n20/D 1.462 (lit.)
• 密度: 1.62 g/mL at 25 °C (lit.)
• SMILES記法: FC(F)(F)Oc1cccc(Br)c1
• InChI: 1S/C7H4BrF3O/c8-5-2-1-3-6(4-5)12-7(9,10)11/h1-4H
• InChI Key: WVUDHWBCPSXAFN-UHFFFAOYSA-N

詳細

詳細

1-Bromo-3-(trifluoromethoxy)benzene undergoes Diels-Alder reaction with lithium diisopropylamide (LDA) in THF and furan, to yield the corresponding 1,4-dihydro-1,4-epoxy-5- or 6-(trifluoromethoxy)naphthalenes.

アプリケーション

1-Bromo-3-(trifluoromethoxy)benzene may be used in the preparation of 1,2-dehydro-3-(trifluoromethoxy)benzene. It may be used in the synthesis of new electronically deficient atropisomeric diphosphine ligand (S)-CF₃O-BiPhep [2,2′-bis(diphenylphosphino)-6,6′-ditrifluoromethoxy-1,1′-biphenyl].

安全性情報

• 保管分類コード: 10 - Combustible liquids
• WGK: WGK 3
• 引火点(°F): 145.4 °F - closed cup
• 引火点(℃): 63 °C - closed cup
• 個人用保護具 (PPE): Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)