Merck
All Photos(1)

5.43804

Supelco

Formic acid 98 - 100%

for HPLC LiChropur

Synonym(s):
Formic acid, Methanoic acid, Formylic acid
Linear Formula:
HCOOH
CAS Number:
Molecular Weight:
46.03
Beilstein:
1209246
MDL number:
EC Index Number:
200-579-1

vapor density

1.6 (vs air)

Quality Level

vapor pressure

44.8 mmHg ( 20 °C)

Assay

≥98% (alkalimetric)

form

liquid

autoignition temp.

1004 °F

expl. lim.

12-38 % (v/v)
57 %

technique(s)

HPLC: suitable

refractive index

n20/D 1.370 (lit.)

pH

2.2 (20 °C, 10 g/L in H2O)

bp

100-101 °C (lit.)
101 °C/1013 hPa

mp

8.2-8.4 °C (lit.)

transition temp

flash point 49.5 °C

density

1.22 g/mL at 25 °C (lit.)

cation traces

Al: ≤0.05 ppm
Ca: ≤0.20 ppm
Cu: ≤0.020 ppm
Fe: ≤2.0 ppm
K: ≤0.10 ppm
Mg: ≤0.50 ppm
Na: ≤0.50 ppm

storage temp.

15-25°C

SMILES string

OC=O

InChI

1S/CH2O2/c2-1-3/h1H,(H,2,3)

InChI key

BDAGIHXWWSANSR-UHFFFAOYSA-N

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Formic acid 98 - 100% for HPLC LiChropur™

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vapor density

1.6 (vs air)

vapor density

1.6 (vs air)

vapor density

1.6 (vs air)

vapor density

<0.3 (25 °C, vs air)

vapor pressure

44.8 mmHg ( 20 °C)

vapor pressure

44.8 mmHg ( 20 °C)

vapor pressure

44.8 mmHg ( 20 °C)

vapor pressure

0.0001 hPa ( 20 °C), 1 mmHg ( 146 °C)

assay

≥98% (alkalimetric)

assay

≥98% (acidimetric), 98-100%

assay

≥98% (alkalimetric)

assay

≥95% (acidimetric), 96%

form

liquid

form

liquid

form

liquid

form

liquid

refractive index

n20/D 1.370 (lit.)

refractive index

n20/D 1.370 (lit.)

refractive index

n20/D 1.370 (lit.)

refractive index

-

pH

2.2 (20 °C, 10 g/L in H2O)

pH

2.2 (20 °C, 10 g/L in H2O)

pH

2.2 (20 °C, 10 g/L in H2O)

pH

0.3 (25 °C, 49 g/L in H2O)

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Legal Information

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1A

Supplementary Hazards

Storage Class Code

3 - Flammable liquids

WGK

WGK 1

Flash Point(F)

121.1 °F

Flash Point(C)

49.5 °C


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PDSCL

Deleterious substance

FSL

Flammable liquids
Type 2 petroleums
Hazardous rank III
Water soluble liquid

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

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