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Safety Information

769517

Sigma-Aldrich

Sodium (meta)periodate

≥99%

Synonym(s):

Sodium periodate

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About This Item

Linear Formula:
NaIO4
CAS Number:
7790-28-5
Molecular Weight:
213.89
EC Number:
232-197-6
MDL number:
MFCD00003534
UNSPSC Code:
12352302
PubChem Substance ID:
329767447
NACRES:
NA.23
grade:
for analytical purposes
form:
crystalline

grade

for analytical purposes

Quality Level

100

Assay

≥99%
99.0-101.0% (RT)

form

crystalline

anion traces

sulfate (SO42-): ≤0.005%

cation traces

Mn: ≤0.0001%

SMILES string

[Na+].[O-]I(=O)(=O)=O

InChI

1S/HIO4.Na/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1

InChI key

JQWHASGSAFIOCM-UHFFFAOYSA-M

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Application

Sodium metaperiodate finds application as catalyst in organic reactions]. For example it is known to catalyze selective sulfonylation of aromatics and the graft copolymerization of acrylonitrile.
Useful reagent for the oxidation of carbohydrates prior to labeling with biotin hydrazide

Analysis Note

Chloride, Chlorate, Bromide, Bromate (as Cl) ≤ 0.01 %

Signal Word

Danger

Hazard Statements

H271,H314,H372,H410

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Ox. Sol. 1 - Skin Corr. 1C - STOT RE 1

Target Organs

thymus gland

Storage Class Code

5.1A - Strongly oxidizing hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 1: Oxidizing solids
Periodates
Hazardous rank I
1st oxidizing solid

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

769517-100G:
769517-25G:
769517-BULK:
769517-VAR:

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Certificates of Analysis (COA)

Lot/Batch Number
BCCH1992
BCCG5366
BCCC4634
BCCC0313
K48778596

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Rout, J., et al.
Journal of Applied Polymer Science, 84, 75-75 (2002)
Sara Nejati et al.
Colloids and surfaces. B, Biointerfaces, 196, 111347-111347 (2020-09-20)
Injectable hydrogels with conductivity are highly desirable as scaffolds for the engineering of various electrical stimuli-responsive tissues, including nerve, muscle, retina, and bone. However, oxygen deprivation within scaffolds can lead to failure by causing cell necrosis. Therefore, an oxygen release
Sodium Periodate Catalyzed Selective Sulfonylation of Aromatics
Bandgar, BP. and Kample, VT.
Chemistry Letters (Jpn), 10, 1066-1067 (2002)
Panpan Li et al.
Carbohydrate polymers, 199, 219-227 (2018-08-26)
Deep eutectic solvents (DESs) are potential green systems that can be used as reagents, extraction agents and reaction media. DESs are often biodegradable, easy to prepare and have low toxicity. In this work, a recyclable DES formed from aminoguanidine hydrochloride
Surya R Banks et al.
Journal of agricultural and food chemistry, 67(37), 10481-10488 (2019-08-23)
Here, we report two methods that chemically modify alginate to achieve neutral-basic pH sensitivity of the resultant hydrogel. The first method involves direct amide bond formation between alginate and 4-(2-aminoethyl)benzoic acid. The second method that arose out of the desire
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