Skip to Content
Merck
All Photos(1)

Key Documents

View All Documentation

Safety Information

692301

Sigma-Aldrich

RuCl2[(R)−DM−BINAP][(R,R)−DPEN]

Synonym(s):

Dichloro[(R)−2,2′−bis[di(3,5−xylyl)phosphino]−1,1′−binaphthyl][(1R,2R)−1,2−diphenylethylenediamine]ruthenium(II)

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Empirical Formula (Hill Notation):
C66H64Cl2N2P2Ru
CAS Number:
220114-38-5
Molecular Weight:
1119.15
MDL number:
MFCD09753028
UNSPSC Code:
12352005
PubChem Substance ID:
329761481
NACRES:
NA.22

form

powder

Quality Level

100

storage temp.

2-8°C

SMILES string

Cl[Ru]Cl.N[C@@H]([C@H](N)c1ccccc1)c2ccccc2.Cc3cc(C)cc(c3)P(c4cc(C)cc(C)c4)c5ccc6ccccc6c5-c7c(ccc8ccccc78)P(c9cc(C)cc(C)c9)c%10cc(C)cc(C)c%10

InChI

1S/C52H48P2.C14H16N2.2ClH.Ru/c1-33-21-34(2)26-43(25-33)53(44-27-35(3)22-36(4)28-44)49-19-17-41-13-9-11-15-47(41)51(49)52-48-16-12-10-14-42(48)18-20-50(52)54(45-29-37(5)23-38(6)30-45)46-31-39(7)24-40(8)32-46;15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12;;;/h9-32H,1-8H3;1-10,13-14H,15-16H2;2*1H;/q;;;;+2/p-2/t;13-,14-;;;/m.1.../s1

InChI key

HYMSONXJNGZZBM-ODQAEMFESA-L

General description

The product is a bis-naphthalene containing phosphine ligand, in conjugation with a ruthenium complex.

Application

Takasago Ligands and Complexes for Asymmetric Reactions
RuCl2[(R)-DM-BINAP][(R,R)-DPEN] can catalyze the enantioselective asymmetric reduction of benzils to form the corresponding chiral 1,2-diols.

Legal Information

Sold in collaboration with Takasago for research purposes only. JP Registration No. 2041996, 2731377, 2935453 JP Application No. 19970359654

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

692301-VAR:
692301-BULK:
692301-100MG:
692301-50MG:

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
MKBW7571V
MKBH6767
06225LH

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Bifunctional transition metal-based molecular catalysts for asymmetric syntheses.
Ikariya T, et al.
Organic & Biomolecular Chemistry, 4(3), 393-406 (2006)

Articles

Takasago Ligands

Hydrogenation, Asymmetric Catalysis, Binap, SEGPHOS®, Aldol reaction, Alkenylation, Arylation, Mannich reaction, Fluorination, Michael addition, Hydrosilylation, Cycloaddition, Takasago

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service